Creation of Nucleophilic Boryl Anions and Their Properties

Yamashita Makoto

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Creation of Nucleophilic Boryl Anions and Their Properties

机译：创造亲核骨髓阴离子及其性质

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A series of anionic boron compounds, possessing a polarized boron metal bond, were synthesized and structurally characterized. Detailed analyses of these boryl anions using NMR spectroscopy, X-ray crystallography, reactivity with electrophiles, and DFT calculations revealed that these compounds have anionic and nucleophilic character on the boron center in contrast to conventional boron-containing molecules with a Lewis acidic character. Some applications of boryl anions toward organic synthesis, organometallic chemistry, and main group chemistry are also described.

机译：合成和结构表征具有偏振硼金属键的一系列阴离子硼化合物。使用NMR光谱，X射线晶体学，与电子手术的反应性和DFT计算的详细分析表明，这些化合物与硼中心的阴离子和亲核特征相比，与含有路易斯酸性特性的常规硼的分子形成对比。还描述了对有机合成，有机金属化学和主要组化学的一些应用。

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《Bulletin of the Chemical Society of Japan》 |2011年第10期|共17页
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Yamashita Makoto;
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正文语种 eng
中图分类化学;
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1. Creation of Nucleophilic Boryl Anions and Their Properties [J] . Yamashita Makoto Bulletin of the Chemical Society of Japan . 2011,第10期

机译：创造亲核骨髓阴离子及其性质
2. Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC-B(CN)(2) [J] . Boeser Richard, Haufe Lisa C., Freytag Matthias, Chemical science . 2017,第9期

机译：完成系列硼 - 亲核氰基硼酸盐：NHC-B型（CN）（2）
3. Lithiumboryl - A Synthon for a Nucleophilic Boryl Anion [J] . Holger Braunschweig Angewandte Chemie . 2007,第12期

机译：硼酸锂-亲核性硼酸阴离子的合成子
4. Octaorgano silsesquioxanes with encapsulated fluoride anion, TBA(F~-@T_8), as a new class of non-coordinating non-nucleophilic supporting electrolytes [C] . Mikhail Syroeshkin, Yu Wang, Mamadou Dieng, Meeting of the Electrochemical Society . 2013

机译：Octaorgano Silsesquioxanes用封装的氟化物阴离子，TBA（F〜 - T_8），作为一种新的非协调非亲核支持电解质
5. Reactions of metal carbonyl anions and Fischer-type transition metal carbene complexes: An investigation of the different sites of nucleophilic attack on Fischer carbenes. [D] . Toomey, Laurence Michael. 1997

机译：羰基金属阴离子与Fischer型过渡金属卡宾配合物的反应：对Fischer carbenes进行亲核攻击的不同位点的研究。
6. Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC–B(CN)2– [O] . Richard Böser, Lisa C. Haufe, Matthias Freytag, 2017

机译：完成一系列硼亲核氰基硼酸盐：NHC–B（CN）2型硼离子–
7. Creation of Nucleophilic Boryl Anions and Their Properties [O] . Makoto Yamashita 2011

机译：创造亲核骨髓阴离子及其性质
8. Micellar Effects Upon Substitutions by Nucleophilic Anions [R] . Bunton, C. A., Moffatt, J. R. 1988

机译：亲核阴离子取代时的胶束效应

Creation of Nucleophilic Boryl Anions and Their Properties

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