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首页> 外文期刊>Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry >A stereodynamic fluorescent probe for amino acids. Circular dichroism and circularly polarized luminescence analysis
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A stereodynamic fluorescent probe for amino acids. Circular dichroism and circularly polarized luminescence analysis

机译:氨基酸的立体荧光探针。 圆形二色性和圆偏振发光分析

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Abstract >The use of stereodynamic probes is becoming one of the leading strategies for the fast and effective determination of enantiomeric excess. Recently, we reported a series of novel molecular architectures based on a modified tris(2‐pyridylmethyl)amine complex (TPMA), which are able to amplify the electronic CD, in the case of Zn(II) assemblies and vibrational CD, in the case of Co(II) assemblies. Herein, we report a structural modification of the ligand with the purpose to obtain a fluorescent chiral probe. The study deals with the synthesis of the novel ligand, the formation of the self‐assembly system with amino acids, and the study of the electronic CD and circularly polarized luminescence. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“main”XML:Lang =“en”> <title类型=“main”>抽象</ title> >使用立体动力探测器正在成为快速有效地确定的主要策略之一 对映体过量。 最近,我们报道了一种基于改性三(2-吡啶甲基)胺络合物(TPMA)的新型分子架构,其能够在Zn(II)组件和振动CD的情况下放大电子CD。 CO(II)组件的情况。 在此,我们报告了配体的结构改性,目的是获得荧光手性探针。 该研究涉及新型配体的合成,与氨基酸形成自组装系统,以及电子CD和圆极化发光的研究。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16290/'>《Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry》</a> <b style="margin: 0 2px;">|</b><span>2018年第1期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Carmo dos Santos Nadia Alessandra&option=202" target="_blank" rel="nofollow">Carmo dos Santos Nadia Alessandra;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Badetti Elena&option=202" target="_blank" rel="nofollow">Badetti Elena;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Licini Giulia&option=202" target="_blank" rel="nofollow">Licini Giulia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abbate Sergio&option=202" target="_blank" rel="nofollow">Abbate Sergio;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Longhi Giovanna&option=202" target="_blank" rel="nofollow">Longhi Giovanna;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zonta Cristiano&option=202" target="_blank" rel="nofollow">Zonta Cristiano;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Dipartimento di Scienze ChimicheUniversità degli Studi di PadovaPadova PD Italy;</p> <p>Dipartimento di Scienze ChimicheUniversità degli Studi di PadovaPadova PD Italy;</p> <p>Dipartimento di Scienze ChimicheUniversità degli Studi di PadovaPadova PD Italy;</p> <p>Department of Molecular and Translational MedicineUniversità di BresciaBrescia BS Italy;</p> <p>Department of Molecular and Translational MedicineUniversità di BresciaBrescia BS Italy;</p> <p>Dipartimento di Scienze ChimicheUniversità degli Studi di PadovaPadova PD Italy;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4812.html" title="结构化学">结构化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CD&option=203" rel="nofollow">CD;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CPL&option=203" rel="nofollow">CPL;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=enantiomeric excess&option=203" rel="nofollow">enantiomeric excess;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=self‐assembly&option=203" rel="nofollow">self‐assembly;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=supramolecular chemistry&option=203" rel="nofollow">supramolecular chemistry;</a> </p> <div class="translation"> 机译:CD;CPL;对映体过量;自组装;超分子化学; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022113646.html">A stereodynamic fluorescent probe for amino acids. 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