The Generation Effect: Cavity Accessibility in Dense-Shell Polyphenylene Dendrimers

Brutschy Malte; Stangenberg Rene; Beer Cornelia; Lubczyk Daniel; Baumgarten Martin; Muellen Klaus; Waldvogel Siegfried R.

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The Generation Effect: Cavity Accessibility in Dense-Shell Polyphenylene Dendrimers

机译：发电效应：致密壳聚苯二甲酯中的空腔可用性

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摘要

Size exclusion is a widespread phenomenon in supra- and macromolecular chemistry. Herein, the size exclusion properties of polyphenylene dendrimers on the surface of high fundamental frequency quartz crystal microbalances are reported. For this purpose, a new dense fifth-generation polyphenylene dendrimer, which was previously not possible owing to the high steric demand of the dendron arms, was synthesized. By increasing the volume and size of subjected analytes an affinity shift from smaller to larger dendrimers can be obtained.

机译：尺寸排除是在同上和大分子化学中的广泛现象。这里，报道了高基频石英晶体微稳压表面上的聚苯内树枝状晶片的尺寸排除性能。为此目的，合成了以前不可能的新密集第五代的聚苯二甲烯树枝状体，其是由于树枝臂的高空间需求而不可能。通过增加受试者分析物的体积和尺寸可以获得从较小到更大的树枝状夹的亲和偏移。

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来源
《ChemPlusChem》 |2015年第1期|共3页
作者
Brutschy Malte; Stangenberg Rene; Beer Cornelia; Lubczyk Daniel; Baumgarten Martin; Muellen Klaus; Waldvogel Siegfried R.;
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作者单位

Johannes Gutenberg Univ Mainz Inst Organ Chem D-55128 Mainz Germany;

Max Planck Inst Polymer Res D-55128 Mainz Germany;

Max Planck Inst Polymer Res D-55128 Mainz Germany;

Johannes Gutenberg Univ Mainz Inst Organ Chem D-55128 Mainz Germany;

Max Planck Inst Polymer Res D-55128 Mainz Germany;

Max Planck Inst Polymer Res D-55128 Mainz Germany;

Johannes Gutenberg Univ Mainz Inst Organ Chem D-55128 Mainz Germany;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
dendrimers; molecular recognition; polyphenylenes; quartz crystal microbalances; supramolecular chemistry;

机译：树枝状大分子;分子识别;聚苯;石英晶体微稳压;超分子化学;

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专利

1. The Generation Effect: Cavity Accessibility in Dense-Shell Polyphenylene Dendrimers [J] . Brutschy Malte, Stangenberg Rene, Beer Cornelia, ChemPlusChem . 2015,第1期

机译：发电效应：致密壳聚苯二甲酯中的空腔可用性
2. Solid-state NMR investigations of molecular dynamics in polyphenylene dendrimers: Evidence of dense-shell packing [J] . Wind M., Saalwachter K., Wiesler UM., Macromolecules . 2002,第27期

机译：固态NMR研究聚亚苯基树枝状大分子中的分子动力学：致密壳堆积的证据
3. Thermodynamic properties of pyridine-containing polyphenylene dendrimers of the first-fourth generations [J] . N. N. Smirnova, A. V. Markin, Yu. A. Zakharova Russian Chemical Bulletin . 2011,第1期

机译：第1-4代含吡啶的聚亚苯基树枝状大分子的热力学性质
4. Fourth Order Connectivity Index of Polyphenylene Dendrimers [C] . Roslan Hasni, Nabeel Ezzulddin Arif National Symposium on Mathematical Sciences . 2013

机译：多聚亚苯胺树枝状大分子的四阶连接指标
5. Trapping dendrimers in inorganic matrices: Formation of silica xerogels with spherical cavities and dendrimer/zinc arsenate lamellar composites. [D] . Lotero, Edgar. 2001

机译：在无机基质中捕获树枝状大分子：形成具有球形空腔的二氧化硅干凝胶和树枝状大分子/砷酸锌层状复合材料。
6. Blue Light Emitting Polyphenylene Dendrimers with Bipolar Charge Transport Moieties [O] . Guang Zhang, Manuel Auer-Berger, Dominik W. Gehrig, 2016

机译：具有双极性电荷传输部分的蓝色发光聚苯撑树枝状聚合物
7. Blue Light Emitting Polyphenylene Dendrimers with Bipolar Charge Transport Moieties [O] . Guang Zhang, Manuel Auer-Berger, Dominik W. Gehrig, 2016

机译：具有双极电荷传输部分的蓝光发光聚亚苯基树枝状大分子
8. Liquid Crystalline Dendrimers: 2. Synthesis of Four Generations of Carbosilane LC Dendrimers with Terminal Methoxyphenylbenzoate Groups. Study of Phase Behaviour Structure and Mobility of mesogenic Groups of LC Dendrimers [R] . Shibaev, V. P. , Boiko, N. I. , Muzafarov, A. M. , 1998

机译：液晶树枝状大分子：2。具有末端甲氧基苯基苯甲酸酯基团的四代碳硅烷LC树枝状大分子的合成。 LC树枝状大分子的介晶基团的相行为结构和迁移率研究

The Generation Effect: Cavity Accessibility in Dense-Shell Polyphenylene Dendrimers

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