Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand

Michaelos Thoe K.; Lant Hannah M. C.; Sharninghausen Liam S.; Craig Stephanie M.; Menges Fabian S.; Mercado Brandon Q.; Brudvig Gary W.; Crabtree Robert H.

首页> 外文期刊>ChemPlusChem >Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand

【24h】

Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand

机译：用抗氧化N，N，O-供体配体的锰配合物的催化氧量进化

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

There is great interest in developing Mn water-splitting catalysts due to their low cost, abundance, and relevance to the oxygen-evolving complex (OEC). Three ligands with highly donating pyridine alkoxide moieties, including 2-(pyridin-2-yl)propan-2-ol (pyalkH), 2,2-(pyridine-2,6-diyl)bis(propan-2-ol) (py-dialkH(2)), and 2-[(2,2-bipyridin)-6-yl]propan-2-ol (bipy-alkH), have been screened with Mn for oxygen-evolution catalysis. Complexes with the ligand bipy-alkH were shown to evolve O-2 when driven by Oxone (potassium peroxymonosulfate). The catalytic mixture generated from the precursor complex [Mn(bipy-alkH)Cl-2] retained activity in unbuffered solution beyond 160h.

机译：由于它们的低成本，丰度和与氧化复合物（OEC）的相关性，对开发Mn水分裂催化剂的兴趣非常兴趣。三种配体，具有高度吡啶醇盐部分，包括2-（吡啶-2-基）丙烷-2-醇（PyalkH），2,2-（吡啶-2,6-二基）双（Propan-2-Ol）（用MN筛选丙烷-2-醇（BiPy-AlkH），丙烷-2-醇（2））和2 - [（2,2-Biphyridin）-6-Y1]，用于氧化催化。当由赭石（过氧化钾硫酸钾）驱动时，显示与配体BiPy-AlkH的复合物。从前体复合物[Mn（BiPy-AlkH）Cl-2产生的催化混合物在超过160h的不缓解溶液中保留活性。

著录项

来源
《ChemPlusChem》 |2016年第10期|共4页
作者
Michaelos Thoe K.; Lant Hannah M. C.; Sharninghausen Liam S.; Craig Stephanie M.; Menges Fabian S.; Mercado Brandon Q.; Brudvig Gary W.; Crabtree Robert H.;
展开▼
作者单位

Yale Univ Dept Chem 225 Prospect St New Haven CT 06511 USA;

Yale Univ Dept Chem 225 Prospect St New Haven CT 06511 USA;

Yale Univ Dept Chem 225 Prospect St New Haven CT 06511 USA;

Yale Univ Dept Chem 225 Prospect St New Haven CT 06511 USA;

Yale Univ Dept Chem 225 Prospect St New Haven CT 06511 USA;

Yale Univ Dept Chem 225 Prospect St New Haven CT 06511 USA;

Yale Univ Dept Chem 225 Prospect St New Haven CT 06511 USA;

Yale Univ Dept Chem 225 Prospect St New Haven CT 06511 USA;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
homogeneous catalysis; manganese; water oxidation; water splitting;

机译：均匀催化;锰;水氧化;水分裂;

相似文献

外文文献
中文文献
专利

1. Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand [J] . Michaelos Thoe K., Lant Hannah M. C., Sharninghausen Liam S., ChemPlusChem . 2016,第10期

机译：用抗氧化N，N，O-供体配体的锰配合物的催化氧量进化
2. Three new coordination complexes of cobalt(III), manganese(II), and copper(II) with N,N,O-donor hydrazone ligands: syntheses and structural characterizations [J] . Shyamapada Shit, Joy Chakraborty, Brajagopal Samanta, Structural Chemistry . 2009,第4期

机译：具有N，N，O供体II配体的钴（III），锰（II）和铜（II）的三种新配位络合物：合成和结构表征
3. Three new coordination complexes of cobalt(III), manganese(II), and copper(II) with N,N,O-donor hydrazone ligands: syntheses and structural characterizations [J] . Shit Shyamapada, Chakraborty Joy, Samanta Brajagopal, Structural Chemistry . 2009,第4期

机译：具有N，N，O供体配体的钴（III），锰（II）和铜（II）的三种新配位络合物：合成和结构表征
4. Ex-situ Spectroscopy Study of Manganese Oxide Catalytic Surfaces under Reaction Conditions Relevant to Oxygen Reduction and Oxygen Evolution [C] . Y. Gorlin, T. F. Jaramillo Polymer Electrolyte Fuel Cells 11 . 2013

机译：与氧还原和氧释放相关的反应条件下锰氧化物催化表面的异位光谱研究
5. Computational study of the oxygen-oxygen bond activation and hydrocarbon oxygenation reactions in the catalytic cycles of the non-heme diiron enzymes and chiral manganese(Salen) complexes. [D] . Khavrutskii, Ilja V. 2004

机译：非血红素二铁酶与手性锰（Salen）配合物催化循环中氧-氧键活化和烃氧合反应的计算研究。
6. Photoassembly of the manganese cluster and oxygen evolution from monomeric and dimeric CP47 reaction center photosystem II complexes [O] . Claudia Büchel, Jim Barber, Gennady Ananyev, 1999

机译：锰簇的光组装和单体和二聚体CP47反应中心光系统II配合物的氧释放
7. Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation‐Resistant N,N,O‐Donor Ligand [O] . Thoe K. Michaelos, Hannah M. C. Lant, Liam S. Sharninghausen, 2016

机译：用抗氧化N，N，O-供体配体的锰配合物的催化氧量进化
8. Ligand-Centered Electron-Transfer Redox Processes for Manganese, Iron, and Cobalt Complexes in Relation to Selected Catalytic Systems. [R] . Richert, S. A. 1989

机译：与选定的催化体系相关的锰，铁和钴配合物的配体中心电子转移氧化还原过程。

Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand

摘要

著录项

相似文献

相关主题

期刊订阅