A new high-pressure polymorph of phosphoric acid

Craig L. Bull; Nicholas P. Funnell; Colin R. Pulham; William G. Marshall; David R. Allan

首页> 外文期刊>Acta Crystallographica, Section B. Structural science, crystal engineering and materials >A new high-pressure polymorph of phosphoric acid

【24h】

A new high-pressure polymorph of phosphoric acid

机译：一种新的磷酸的高压多晶型物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The high-pressure structural behaviour of phosphoric acid is described. A compression study of the monoclinic phase, using neutron powder diffraction and X-ray single-crystal diffraction, shows that it converts to a previously unobserved orthorhombic phase on decompression. Compression of this new phase is reported up to 6.3 GPa. The orthorhombic phase is found to be more efficiently packed, with reduced void space, resulting in a larger bulk modulus. Molecule-molecule interaction energies reveal a more extensive network of increased attractive forces in the orthorhombic form relative to the monoclinic form, suggesting greater thermodynamic stability.

机译：描述了磷酸的高压结构行为。使用中子粉末衍射和X射线单晶衍射的单斜相的压缩研究表明，它转化为先前未被检测的正交相位的减压。据报道，这种新阶段的压缩高达6.3 GPA。发现正交相位更有效地填充，具有降低的空隙空间，导致较大的体积模量。分子分子相互作用能量揭示了一种相对于单斜晶形式以正交形式增加的更广泛的含量吸引力，表明了更大的热力学稳定性。

著录项

来源
《Acta Crystallographica, Section B. Structural science, crystal engineering and materials》 |2017年第6期|共7页
作者
Craig L. Bull; Nicholas P. Funnell; Colin R. Pulham; William G. Marshall; David R. Allan;
展开▼
作者单位

ISIS Facility STFC Rutherford Appleton Laboratory Harwell Science and Innovation Campus Chilton Didcot Oxfordshire OX11 0QX UK;

ISIS Facility STFC Rutherford Appleton Laboratory Harwell Science and Innovation Campus Chilton Didcot Oxfordshire OX11 0QX UK;

EaStCHEM School of Chemistry Joseph Black Building David Brewster Road Edinburgh EH9 3FJ UK;

ISIS Facility STFC Rutherford Appleton Laboratory Harwell Science and Innovation Campus Chilton Didcot Oxfordshire OX11 0QX UK;

Diamond Light Source Ltd Diamond House Harwell Science and Innovation Campus Didcot Oxfordshire OX11 0DE UK.;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
high pressure; neutron powder diffraction; X-ray single-crystal diffraction; phosphoric acid; polymorph;

机译：高压;中子粉末衍射;X射线单晶衍射;磷酸;多晶型;

相似文献

外文文献
中文文献
专利

1. A new high-pressure polymorph of phosphoric acid [J] . Bull Craig L., Funnell Nicholas P., Pulham Colin R., Acta crystallographica. Section F, Structural biology communications . 2017,第6期

机译：一种新的磷酸的高压多晶型物
2. High-Pressure Accelerated Enantioselective Addition of Indoles to Trifluoromethyl Ketones with a Low Loading of Chiral BINOL-Derived Phosphoric Acid [J] . ChemCatChem . 2017,第13期

机译：高压加速对三氟甲基酮的吲哚加入吲哚，具有低负荷的手性甲醇衍生的磷酸
3. The corrosion of alloy 625 (NiCr22Mo9Nb; 2.4856) in high-temperature, high-pressure aqueous solutions of phosphoric acid and oxygen. corrosion at sub- and supercritical temperatures [J] . P. Kritzer, N. Boukis, E. Dinjus Materials and Corrosion . 1998,第11期

机译：625合金（NiCr22Mo9Nb; 2.4856）在磷酸和氧气的高温高压水溶液中的腐蚀。亚临界和超临界温度下的腐蚀
4. Effects of Phosphoric Acid Concentration on Platinum Catalyst and Phosphoric Acid Hydrogen Pump Performance [C] . S. J. Buelte, D. J. Lewis, G. A. Eisman Polymer Electrolyte Fuel Cells 11 . 2013

机译：磷酸浓度对铂催化剂和磷酸氢泵性能的影响
5. Effects of Phosphoric Acid Concentration on Platinum Catalyst and Phosphoric Acid Hydrogen Pump Performance. [D] . Buelte, Steve. 2011

机译：磷酸浓度对铂催化剂和磷酸氢泵性能的影响。
6. A new high-pressure polymorph of phosphoric acid [O] . Craig L. Bull, Nicholas P. Funnell, Colin R. Pulham, -1

机译：一种新型的磷酸高压多晶型物
7. A new high-pressure polymorph of phosphoric acid [O] . Craig L. Bull, Nicholas P. Funnell, Colin R. Pulham, 2017

机译：一种新的磷酸高压多晶型物

A new high-pressure polymorph of phosphoric acid

摘要

著录项

相似文献

相关主题

期刊订阅