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首页> 外文期刊>Crystal growth & design >Tubular arrangement of 1,3-alternate calix[4]arene with bipyridines: A platform for [2 ± 2] photocyclization
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Tubular arrangement of 1,3-alternate calix[4]arene with bipyridines: A platform for [2 ± 2] photocyclization

机译:1,3-交替杯[4]芳烃与联吡啶的管状排列:[2±2]光环化的平台

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摘要

By using a 1,3-alternate conformation of calix[4]arene tetrabenzoic acid (H_4CTB), a pair of 4,4'- bipyridine has been aligned forming a cocrystallized onedimensional tubular product 1. Inspired by this result, the 1,3- alternate H_4CTB has been utilized as 'clips' to anchor the C? C bond pairs of 4,4'-bipyridylethene to give an isotypical Hbonded tubular product 2 which undergoes the solid-state photodimerization.
机译:通过使用杯[4]亚芳基四苯甲酸(H_4CTB)的1,3-交替构象,将一对4,4'-联吡啶排列成共结晶的一维管状产物1。受此结果的启发,1,3 -备用H_4CTB已被用作固定C的“片段”?通过4,4'-联吡啶乙烯的C键对,得到同型氢键管状产品2,该产品进行了固态光二聚化。

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