Penta- and Decafluorinated Dibenzalacetones: Synthesis, Crystal Structure, and Cocrystallization Experiments

Anke Schwarzer; Edwin Weber

首页> 外文期刊>Crystal growth & design >Penta- and Decafluorinated Dibenzalacetones: Synthesis, Crystal Structure, and Cocrystallization Experiments

【24h】

Penta- and Decafluorinated Dibenzalacetones: Synthesis, Crystal Structure, and Cocrystallization Experiments

机译：五氟和十氟二苯并丙酮：合成，晶体结构和共结晶实验

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The nonfluorinated parent dibenzalacetone 1 as well as the corresponding penta- (2) and decafluorinated (3) derivative compounds were prepared, crystallized, and subjected to co-crystallization experiments. Only 3 yielded a 1:1 co-crystal with 1, while 2 did not form cocrystals with either 1 or 3. Powder X-ray diffraction patterns were determined to verify the cocrystallization experiments. The influence of the fluorine on the molecular geometry and crystal packing were studied and comparatively discussed. Conclusions with reference to the priority of Ar···Ar~F contact modes in the crystalline packing being in competition with other fluorine and non-fluorine involved supramolecular interactions were drawn.

机译：制备非氟化母体二苯并丙酮1以及相应的五-（2）和十-氟化（3）衍生物，进行结晶，然后进行共结晶实验。只有3个与1个产生了1：1的共晶，而2个没有与1个或3个形成共晶。确定了粉末X射线衍射图以验证共结晶实验。研究并比较了氟对分子几何形状和晶体堆积的影响。得出的结论是，在晶体堆积中Ar··Ar〜F的接触方式优先与其他氟和非氟涉及的超分子相互作用竞争。

著录项

来源
《Crystal growth & design》 |2014年第5期|共8页
作者
Anke Schwarzer; Edwin Weber;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
diffraction; supramolecular; priority;

机译：衍射;超分子;优先;

相似文献

外文文献
中文文献
专利

1. Penta- and Decafluorinated Dibenzalacetones: Synthesis, Crystal Structure, and Cocrystallization Experiments [J] . Anke Schwarzer, Edwin Weber Crystal growth & design . 2014,第5期

机译：五氟和十氟二苯并丙酮：合成，晶体结构和共结晶实验
2. Tri-p-tolylphosphine-cyclopalladated ferrocenylpyrlmldine complexes: synthesis, crystal structures, catalytic activity, and a palladacycle cocrystallization adduct [J] . Chen Xu, Yan-Xia Lu, Xin-Hua Lou Transition Metal Chemistry . 2011,第6期

机译：三对甲苯基膦-环钯的二茂铁基吡咯烷基配合物：合成，晶体结构，催化活性和palladacycle共结晶加合物
3. Tri-p-tolylphosphine-cyclopalladated ferrocenylpyrimidine complexes: synthesis, crystal structures, catalytic activity, and a palladacycle cocrystallization adduct [J] . Chen Xu, Yan-Xia Lu, Xin-Hua Lou, Transition Metal Chemistry . 2011,第6期

机译：三对甲苯基膦-环钯的二茂铁基嘧啶配合物：合成，晶体结构，催化活性和palladacycle共结晶加合物
4. Synthesis and cocrystallization of bi-1,2,5-oxadiazole nitro derivatives [C] . Leonid Fershtat, Margarita Epishina, Alexander Larin, Seminar on New Trends in Research of Energetic Materials . 2017

机译：双1,2,5-恶二唑硝基衍生物的合成和共结晶
5. Peptide synthesis and characterization: Part 1. Synthesis and characterization of cyclic pseudopeptide analogs of endothelin antagonist BQ-123. Part 2. Comparative study of mild cleavage techniques for solid-phase synthesis of penta-, tetra-, and tri-peptides. [D] . Ingram, Darlene D. 2004

机译：肽的合成和表征：第1部分。内皮素拮抗剂BQ-123的环状假肽类似物的合成和表征。第2部分。五肽，四肽和三肽固相合成的轻度裂解技术的比较研究。
6. In silico screening of dicarboxylic acids for cocrystallization with phenylpiperazine derivatives based on both cocrystallization propensity and solubility advantage [O] . Piotr Cysewski -1

机译：基于共结晶倾向和溶解度优势对二羧酸与苯基哌嗪衍生物进行共结晶进行计算机筛选
7. Synthesis of Tin Oxide Nanostructures Using Hydrothermal Method and Optimization of its Crystal size by Using Statistical Design of Experiment [O] . Akhir Maisara A.M., Mohamed Khairudin, Lee H.L., 2016

机译：水热法合成氧化锡纳米结构及实验统计设计优化其晶体尺寸
8. Cocrystallization in blends of poly(butylene terephthalate) and poly(ester-ether) segmented block copolymers. [R] . K. P. Gallagher X. Zhang J. P. Runt G. Huynh-ba J. S. Lin 1991

机译：在聚（对苯二甲酸丁二醇酯）和聚（酯 - 醚）嵌段共聚物的共混物中共结晶。

Penta- and Decafluorinated Dibenzalacetones: Synthesis, Crystal Structure, and Cocrystallization Experiments

摘要

著录项

相似文献

相关主题

期刊订阅