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In Situ Monitoring of Crystallization Processes Using Synchrotron X-ray Diffraction: The Search for Structural Precursors

机译:使用同步加速器X射线衍射原位监测结晶过程:寻找结构前体

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摘要

Preliminary in situ SAXS and WAXD studies of the nucleation of molecular crystals from undercooled melts and supersaturated solutions are reported. Supersaturated solutions showed no evidence of long-range ordering prior to the appearance of crystals, while in single component melts the appearance of short-lived metastable crystalline and liquid crystalline states are consistent with precrystalline molecular assembly.
机译:据报道,对过冷熔体和过饱和溶液中的分子晶体成核进行了原位SAXS和WAXD研究。过饱和溶液没有显示出晶体出现之前的长程有序迹象,而在单组分熔体中,短暂存在的亚稳态晶体和液晶状态与预晶体分子组装相一致。

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