Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks

Wenbin Lin; Owen R. Evans; Yong Cui

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Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks

机译：锌和吡啶甲酸镉镉配位网络的合成及X射线结构

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New zinc(II) and cadmium(II) coordination polymers with 3-[2-(3-pyridyl)ethenyl]benzoato (L) bridging ligands have been synthesized by treating the metal salts and 3-[2-(3-pyridyl)ethenyl]benzonitrile under hydro-(solvo)thermal conditions. [Zn(L)_2]250L?pyridine), 1, adopts a 1D polymeric structure built from mutually perpendicular 22-membered macrocycles. Large open channels formed in 1 are filled with included pyridine guest molecules. Both [Cd_2(L)_3(NO_3)], 2, and [Cd_4(L)_6(ClO_4)_2(MeOH)_2]250L?H_2O), 3, adopt complicated 2D polymeric structures that are built from carboxylate-bridged tetracadmium and dicadmium building units, respectively. Crystal data for 1: triclinic space group P1-bar, a = 8.601(1), b = 12.364(1), c = 14.224(1) A, α = 72.687(1), β = 88.118(1), γ = 71.679(1)°, Z = 2. Crystal data for 2: triclinic space group P1-bar, a = 10.675(1), b = 12.671(1), c = 14.838(1) A, α = 74.772(1), β = 88.283(1), γ = 73.671(1)°, Z = 2. Crystal data for 3: monoclinic space group P2_1, a = 13.165(3), b = 20.119(9), c = 15.446(6) A, β = 95.19(3), Z = 2.

机译：通过处理金属盐和3- [2-（3-吡啶基）金属，合成了具有3- [2-（3-吡啶基）乙烯基]苯并（L）桥联配体的新型锌（II）和镉（II）配位聚合物。乙烯-苯甲腈在水（溶剂）热条件下。 [Zn（L）_2]250L？吡啶）1采用由相互垂直的22元大环构成的一维聚合物结构。 1中形成的大的开放通道中充满了吡啶客体分子。 [Cd_2（L）_3（NO_3）] 2和[Cd_4（L）_6（ClO_4）_2（MeOH）_2]250L？H_2O）3均采用复杂的二维聚合物结构，该结构由羧酸桥联而成四镉和二镉建筑单元。 1：三斜晶空间群P1-bar的晶体数据，a = 8.601（1），b = 12.364（1），c = 14.224（1）A，α= 72.687（1），β= 88.118（1），γ= 71.679（1）°，Z =2。2晶格空间群P1-bar的晶体数据，a = 10.675（1），b = 12.671（1），c = 14.838（1）A，α= 74.772（1），β= 88.283（1），γ= 73.671（1）°，Z =2。3个晶体的晶体数据：单斜空间群P2_1，a = 13.165（3），b = 20.119（9），c = 15.446（6） A，β= 95.19（3），Z = 2。

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《Crystal growth & design》 |2002年第5期|共6页
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Wenbin Lin; Owen R. Evans; Yong Cui;
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1. Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks [J] . Wenbin Lin, Owen R. Evans, Yong Cui Crystal growth & design . 2002,第5期

机译：锌和吡啶甲酸镉镉配位网络的合成及X射线结构
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3. Three-dimensional manganese(II) coordination polymers based on m-pyridinecarboxylates: Synthesis, X-ray structures, and magnetic properties [J] . Lin WB., Wang ZY., Yee GT., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000,第18期

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Synthesis and X-ray Structures of Zinc and Cadmium Pyridinecarboxylate Coordination Networks

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