Varying the Frameworks of Novel Silver(I) Coordination Polymers with Thioethers by Altering the Backbone or Terminal Groups of Ligands

Xian-He Bu; Wen-Feng Hou; Miao Du; Wei Chen; Ruo-Hua Zhang

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Varying the Frameworks of Novel Silver(I) Coordination Polymers with Thioethers by Altering the Backbone or Terminal Groups of Ligands

机译：通过改变配体的骨架或端基改变含硫醚的新型银（I）配位聚合物的框架

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A series of novel silver-thioether metal-organic supramolecular architectures forming different frameworks are constructed by the direct reactions of Ag~I perchlorate with a series of di- or trithioether ligands which are closely related in structure. In the crystal structures of the four complexes, a variety of coordination models of the Ag~I centers due to the conformation freedom or steric hindrance have been observed, indicating that the nature of the ligands is a determining factor in controlling the structural topology of the metal-organic supramolecular architectures.

机译：通过Ag-1高氯酸盐与一系列结构上密切相关的二硫或三硫醚配体的直接反应，构建了形成不同骨架的一系列新颖的银-硫醚金属-有机超分子结构。在这四个配合物的晶体结构中，由于构象自由或空间位阻，已观察到各种Ag〜I中心的配位模型，这表明配体的性质是控制分子结构的决定因素。金属有机超分子结构。

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《Crystal growth & design》 |2002年第4期|共5页
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Xian-He Bu; Wen-Feng Hou; Miao Du; Wei Chen; Ruo-Hua Zhang;
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正文语种 eng
中图分类晶体学;
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1. Varying the Frameworks of Novel Silver(I) Coordination Polymers with Thioethers by Altering the Backbone or Terminal Groups of Ligands [J] . Xian-He Bu, Wen-Feng Hou, Miao Du, Crystal growth & design . 2002,第4期

机译：通过改变配体的骨架或端基改变含硫醚的新型银（I）配位聚合物的框架
2. Varying the Frameworks of Novel Silver(I) Coordination Polymers with Thioethers by Altering the Backbone or Terminal Groups of Ligands [J] . Xian-He Bu, Wen-Feng Hou, Miao Du, Crystal growth & design . 2002,第4期

机译：通过改变配体的骨架或端基改变含硫醚的新型银（I）配位聚合物的框架
3. Varying the frameworks of coordination polymers with (CuI)_4 cubane cluster by altering terminal groups of thioether ligands [J] . Chuang Xie, Lina Zhou, Wenxiu Feng, Journal of Molecular Structure . 2009,第1a3期

机译：通过改变硫醚配体的末端基团来改变具有（CuI）_4古巴簇的配位聚合物的骨架
4. Luminescence Properties of Organometallic/Coordination Oligomers and Polymers Containing Diphosphine and Diisocyanide Assembling Ligands: Comparison between Mononuclear Model Complexes and Polymers [C] . Pierre D. Harvey Macromolecular Symposia 209; Organometallic and Coordination Clusters and Polymers: Syntheses and Applications Symposium; 20040529-0601; London(CA) . 2004

机译：有机金属/配位低聚物和含二膦和二异氰酸酯组装配体的聚合物的发光性质：单核模型配合物和聚合物之间的比较。
5. The influence of the thiol, disulfide and thioether sulfur ligand coordination in copper(I) dioxygen chemistry involving adduct formation and sulfur ligand oxidative chemistry. [D] . Lee, Yunho. 2007

机译：硫醇，二硫化物和硫醚硫配体配位的影响在涉及加合物形成和硫配体氧化化学的铜（I）双氧化学中。
6. Crystal structure of a helical silver(I) coordination polymer based on an unsymmetrical dipyridyl ligand: catena-polysilver(I)-μ-N-(pyridin-4-ylmethyl)pyridine-3-amine-κ2N:N′ tetrafluoridoborate methanol hemisolvate [O] . Suk-Hee Moon, Youngjin Kang, Ki-Min Park 2015

机译：基于不对称二吡啶基配体的螺旋银（I）配位聚合物的晶体结构：链状聚银（I）-μ-N-（吡啶-4-基甲基yl基）吡啶-3-胺-κ2N：N四氟硼硼酸甲醇半溶剂化物
7. Silver(I) and Thioether-bis(pyrazolyl)methane Ligands: The Correlation between Ligand Functionalization and Coordination Polymer Architecture [O] . Irene Bassanetti, Corrado Atzeri, Dario Alberto Tinonin, 2016

机译：银（I）和硫代醚 - 双（吡唑基）甲烷配体：配体官能化与配位聚合物结构之间的相关性
8. COORDINATION POLYMERS WITH INORGANIC BACKBONES FORMED BY DOUBLE-BRIDGING OF TETRAHEDRAL ELEMENTS [R] . B. P. Block, Selwyn H. Rose, C. W. Schaumann 1962

机译：由四面体元素双桥构成的无机背衬的配位聚合物

Varying the Frameworks of Novel Silver(I) Coordination Polymers with Thioethers by Altering the Backbone or Terminal Groups of Ligands

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