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首页> 外文期刊>Crystal growth & design >Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba-3(ZnB5O10)PO4
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Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba-3(ZnB5O10)PO4

机译:Ba-3(ZnB5O10)PO4的顶晶溶液晶体生长,形貌,光学和热学性质

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摘要

Ba-3(ZnB5O10)PO4 (BZBP) single crystals were grown successfully by a top-seeded solution growth method. High-resolution X-ray diffraction rocking curve measurements reveal a full width at half-maximum of 34.56 '' of a BZBP single crystal grown from a [101]-oriented seed. The refractive indices from the UV to the near infrared region were measured, and revealed a birefringence of 0.04179-0.03059 in the wavelength range of 253.6-2325.4 nm. In addition the type-I and type-II phase-matching range for second and third harmonic generation were calculated based on the fitted Sellmeier equations. In order to further evaluate the potential application of Ba-3(ZnB5O10)PO4, the thermal properties including specific heat, thermal diffusivity, and thermal conductivity were also measured along different crystallographic axes.
机译:通过顶部种子溶液生长法成功地生长了Ba-3(ZnB5O10)PO4(BZBP)单晶。高分辨率X射线衍射摇摆曲线测量揭示了从[101]定向晶种生长的BZBP单晶的半峰全宽为34.56英寸。测量了从UV到近红外区域的折射率,并且在253.6-2325.4nm的波长范围内显示出0.04179-0.03059的双折射。此外,基于拟合的Sellmeier方程计算了用于二次谐波和三次谐波的I型和II型相位匹配范围。为了进一步评估Ba-3(ZnB5O10)PO4的潜在应用,还沿着不同的晶体学轴测量了包括比热,热扩散系数和热导率在内的热性能。

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