Synthesis and Structural Characterization of a Cobalt Coordination Polymer with Formate and Bis(4-(1H-imidazol-1-yl)phenyl)methanone Ligands

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Synthesis and Structural Characterization of a Cobalt Coordination Polymer with Formate and Bis(4-(1H-imidazol-1-yl)phenyl)methanone Ligands

机译：甲酸盐和双（4-（1H-咪唑-1-基）苯基）甲酮配体的合成与结构表征钴配位聚合物

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A cobalt coordination polymer, {[Co(L-1)(2)(H2O)(2)] center dot (HCOO)(2) center dot H2O}(n), where L-1 is a bis(4-(1H-imidazol-1-yl)phenyl)methanone, has been synthesized and characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The crystal crystallizes in the triclinic sp. gr. with the unit cell parameters a = 7.9504(6), b = 10.0231(7), c = 13.3129(8) angstrom, and alpha = 88.399(5)degrees, beta = 75.310(6)degrees, gamma = 79.179(6)degrees, Z = 1. The Co2+ ion has a distorted octahedral environment with two O atoms from two water molecules and four N atoms from four L-1 ligands. A thermal stability of polymer has been discussed.

机译：钴配位聚合物，{[CO（L-1）（2）（2）（2）（2））中心点（HCOO）（2）中心点H2O}（N），其中L-1是双（4-（ 1H-咪唑-1-基）苯基）甲酮，通过红外光谱，元素分析和单晶X射线衍射合成并表征。晶体在三壁SP中结晶。 GR。用单元电池参数A = 7.9504（6），B = 10.0231（7），C = 13.3129（8）埃，α= 88.399（5）度，β= 75.310（6）度，γ= 79.179（6） Z = 1. CO 2 +离子具有扭曲的八面体环境，具有来自两个水分子的两个原子和来自四个L-1配体的四个N原子。已经讨论了聚合物的热稳定性。

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《Crystallography reports》 |2019年第7期|共4页
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1. Synthesis and Structural Characterization of a Cobalt Coordination Polymer with Formate and Bis(4-(1H-imidazol-1-yl)phenyl)methanone Ligands [J] . Crystallography reports . 2019,第7期

机译：甲酸盐和双（4-（1H-咪唑-1-基）苯基）甲酮配体的合成与结构表征钴配位聚合物
2. Synthesis and structural characterization of two coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl) methanone and 5-(tert-butyl)isophthalate ligands [J] . Wang Gao-Feng, Sun Shu-Wen, Wang Wei-Bing, Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2019,第3期

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3. Structural Characterization of a Zinc(II) Bishexafluoroacetylacetonate Coordination Polymer with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands [J] . Wang G. -F., Sun S. -W. Journal of structural chemistry . 2018,第3期

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4. Synthesis, characterization, magnetic properties of cobalt coordination polymer based on 4,4'-Oxybisbenzoic acid and 1,4-bis(pyrid-4-yl)benzene [C] . Fengping Xiao, Peng Hu International Conference on Material Science, Energy and Environmental Engineering . 2017

机译：基于4,4'-氧基苯甲酸和1,4-双（Pyrid-4-基）苯的钴配位聚合物的合成，表征，磁性性能
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机译：新型偶氮席基配体3,4-BIS的一种过渡金属配合物的合成与表征（（（1E，2E）-2 - （（2 - （（（（（（（Z） - （（（（Z） - （3-羟基苯基）二亚苯基）萘-1-基）氨基）乙基）氨基）氨基）-1,2-二苯基乙烯）氨基）苯基）（苯基）甲酮

Synthesis and Structural Characterization of a Cobalt Coordination Polymer with Formate and Bis(4-(1H-imidazol-1-yl)phenyl)methanone Ligands

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