Crystal Structure of New Compound of Platinum: PtLa6(La-9,Sr-3)(Pt0.9Cu0.1)(4)O-42

Kashaev A. A.; Zelbst E. A.; Fundamensky V. S.

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Crystal Structure of New Compound of Platinum: PtLa6(La-9,Sr-3)(Pt0.9Cu0.1)(4)O-42

机译：新型铂化合物的晶体结构：PTLA6（LA-9，SR-3）（PT0.9CU0.1）（4）O-42

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?The crystal structure of new oxide PtLa6(La9Sr3)(Pt0.9Cu0.1)(4)O-42 is a three-dimensional framework, formed by chains of regular octahedra Pt1 and nine-vertex polyhedra La1, extended along coordinate axes. The framework is filled with regular oxygen octahedral, containing Pt2 atoms (Pt0.9Cu0.1) inside, and ten-vertex polyhedra La2 (La,Sr), located along diagonals. The Pt1?(6) octahedron shares vertices with only La1 polyhedra, while the other polyhedra share edges and faces. A framework of similar type was established in the LiFeLaO compound, which differs significantly by the composition and structure of chains of Fe?(6) octahedra and La1 polyhedra. Previously similar chains of polyhedra and octahedra were found in Cu(La,Sr)(2)O-4 and (Cu,Pt)(La,Sr)(2)O-4 chain structures.

机译：？新氧化物PTLA6（LA9SR3）（PT0.9CU0.1）（4）O-42的晶体结构是由沿坐标轴延伸的常规八面体PT1和九个顶点多面体LA1的链形成的三维框架。该框架填充有规则的氧八面体，含有PT2原子（PT0.9CU0.1），位于沿对角线的10个顶点多面体LA2（LA，SR）。 PT1？（6）八面体共享顶点，只有LA1 Polyhedra，而另一个多面体共用边缘和面孔。在Lifelao化合物中建立了类似类型的框架，其通过Fe的链条的组成和结构显着不同？（6）八面体和LA1多面体。在Cu（La，Sr）（2）O-4和（Cu，Pt）（La，Sr）（2）O-4链结构中，发现了类似的多面体和八面体的链。

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《Crystallography reports》 |2019年第1期|共4页
作者
Kashaev A. A.; Zelbst E. A.; Fundamensky V. S.;
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Russian Acad Sci Inst Earth Crust Siberian Branch Irkutsk 664011 Russia;

Irkutsk State Univ Pedag Inst Irkutsk 664003 Russia;

St Petersburg State Technol Inst St Petersburg 190013 Russia;

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Crystal Structure of New Compound of Platinum: PtLa6(La-9,Sr-3)(Pt0.9Cu0.1)(4)O-42

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