Structural diversity in the crystalline complexes of para-sulfonato- calix[4]arene with bipyridinium derivatives

Danylyuk O.; Le?niewska B.; Suwinska K.; Matoussi N.; Coleman A.W.

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Structural diversity in the crystalline complexes of para-sulfonato- calix[4]arene with bipyridinium derivatives

机译：对砜基杯[4]芳烃与联吡啶衍生物的晶体配合物的结构多样性

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The solid-state structures of eight complexes between para-sulfonato- calix[4]arene (C4S) and bipyridinium derivatives, 4,4′-bipyridine (BP), 1,2-bis(4-pyridyl)ethane (BPE), and 1,3-bis(4-pyridyl)propane (BPP), have been determined. All the complexes show high degrees of solvation, involving water and ethanol or methanol or acetone. The observed host/guest stoichiometry is determined in part by the nature of the solvent. A wide range of noncovalent interactions are observed in the various complexes, with the dominant interaction being hydrogen bonding and aromatic-aromatic stacking.

机译：对-磺基-杯[4]芳烃（C4S）和联吡啶衍生物，4,4'-联吡啶（BP），1,2-双（4-吡啶基）乙烷（BPE），和1,3-双（4-吡啶基）丙烷（BPP）已确定。所有的配合物都表现出高度的溶剂化作用，涉及水和乙醇或甲醇或丙酮。观察到的宿主/客体的化学计量部分取决于溶剂的性质。在各种络合物中观察到广泛的非共价相互作用，主要的相互作用是氢键和芳族-芳族堆积。

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《Crystal growth & design》 |2010年第10期|共8页
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Danylyuk O.; Le?niewska B.; Suwinska K.; Matoussi N.; Coleman A.W.;
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1. Structural diversity in the crystalline complexes of para-sulfonato- calix[4]arene with bipyridinium derivatives [J] . Danylyuk O., Le?niewska B., Suwinska K., Crystal growth & design . 2010,第10期

机译：对砜基杯[4]芳烃与联吡啶衍生物的晶体配合物的结构多样性
2. Structural analysis of calix[n]arene-iron(III) complexes (n = 4,6,8) and thermal decomposition of the parent calix[n]arenes [J] . HASALETTIN DELIGOZ, OZLEM OZEN, GULBANU KOYUNDERELI CILGI Journal of Coordination Chemistry . 2007,第1期

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3. Structural diversity of methyl-substituted inclusion complexes of calix[5]arene [J] . Clark TE, Makha M, Sobolev AN, Crystal growth & design . 2007,第10期

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4. Facilitated transport of cations through liquid membrane with calix 4 arenes and O-alkylated calix 4 arenes as carriers [C] . B.Serban, C.Nechifor, G.Nechifor 12th Romanian International Conference on Chemistry and Chemical Engineering Sep 13-15, 2001 Bucharest, Romania . 2001

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Structural diversity in the crystalline complexes of para-sulfonato- calix[4]arene with bipyridinium derivatives

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