Structural diversity of methyl-substituted inclusion complexes of calix[5]arene

Clark TE; Makha M; Sobolev AN; Dalgarno SJ; Atwood JL; Raston CL

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Structural diversity of methyl-substituted inclusion complexes of calix[5]arene

机译：杯[5]芳烃的甲基取代包合物的结构多样性

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The three isomers of xylene form inclusion complexes with p-H-calix[5]arene with different spatial interplay of the cavitands, which is relevant to using crystallization as a means of separating mixtures of o-, m-, and p-xylenes. Competition experiments involving mixtures of o-/m-xylene, o-/p-xylene, and m-/p-xylene and a mixture of all three isomers showed some selectivity in the inclusion of the xylenes with p-H-calix[5]arene according to the inequality m- > o- > p-xylene. Also reported are the toluene and mesitylene solvates, which are isostructural with the o-xylene and m-xylene inclusion complexes, respectively.

机译：二甲苯的三种异构体与对-H-杯[5]芳烃形成包合配合物，空化分子具有不同的空间相互作用，这与使用结晶作为分离邻，间和对二甲苯混合物的手段有关。竞争实验涉及邻/间二甲苯，邻/对二甲苯和间-对二甲苯的混合物以及所有三种异构体的混合物，这些实验表明在将二甲苯与pH-calix [5]芳烃混入时具有一定的选择性根据不等式m-> o->对二甲苯。还报道了甲苯和均三甲苯溶剂合物，它们分别与邻二甲苯和间二甲苯包合物形成同构。

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《Crystal growth & design》 |2007年第10期|共7页
作者
Clark TE; Makha M; Sobolev AN; Dalgarno SJ; Atwood JL; Raston CL;
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正文语种 eng
中图分类晶体学;
关键词
MOLECULAR-STRUCTURE; SOLID-STATE; FUNCTIONALIZED MACROCYCLES; CH/PI INTERACTION; CRYSTAL; CONFINEMENT; SEPARATION; ADSORPTION; CLATHRATE; BENZENE;

机译：分子结构;固态;功能大环;CH / PI相互作用;结晶;约束;分离;吸附;包合物;苯;

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1. Structural diversity of methyl-substituted inclusion complexes of calix[5]arene [J] . Clark TE, Makha M, Sobolev AN, Crystal growth & design . 2007,第10期

机译：杯[5]芳烃的甲基取代包合物的结构多样性
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3. Structural diversity in the crystalline complexes of para-sulfonato- calix[4]arene with bipyridinium derivatives [J] . Danylyuk O., Le?niewska B., Suwinska K., Crystal growth & design . 2010,第10期

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4. Self-Inclusion Phenomenon of Calix4arene Ruthenium and Rhodium Complexes [C] . Youichi Ishii, Shinji Onozaki, Kosuke Fujimoto Symposium on Organometallic Chemistry . 2006

机译：CALIX 4芳烃钌和铑配合物的自掺杂现象
5. Structural Characterization, Olefin Polymerization, and Arene Hydrogenation Properties of Group 4 Complexes Supported on Highly Acidic Sulfated Aluminas. [D] . Williams, Linda Ann. 2011

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6. Syntheses and structural studies of calix4arene–nucleoside and calix4arene–oligonucleotide hybrids [O] . Su Jeong Kim, Byeang Hyean Kim 2003

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Structural diversity of methyl-substituted inclusion complexes of calix[5]arene

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