A Two-Dimensional Coordination Polymer Based on 1,1 ':4 ', 1'-Terphenyl-2 ',4,4',5 '-tetracarboxylate

Yin Xiu-Ju; Fu Yong

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A Two-Dimensional Coordination Polymer Based on 1,1 ':4 ', 1'-Terphenyl-2 ',4,4',5 '-tetracarboxylate

机译：基于1,1'：4'，1“ - 替苯基-2”，4,4“，5' - 1-羧酸盐的二维配位聚合物

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摘要

The coordination polymer, [MnL0.5(H2O)(phen)](n) (H4L = l,1':4',l"-terphenyl-2',4,4",5'-tetracarboxylic acid,phen = 1,10-phenanthroline), has been solvothermal synthesized and structurally characterized by single-crystal X-ray diffraction. Complex crystallizes in triclinic sp. gr. Pl=1_ with Z = 2. Two carboxylate oxygen atoms in the central phenyl rings from two mu(6)-L4- ligands doubly-bridge two Mn(II) ions to form the dinuclear Mn-2(Ocoo-)(2) unit. Each dinuclear Mn-2(Ocoo-)(2) unit links four L4- ligands and each L4- ligand bridges four dinuclear Mn-2(Ocoo-)(2) units to generate a 2D coordination network, which can be rationalized as a binodal (4,4) topological network by considering the dinuclear Mn-2(Ocoo-)(2) units and L4- ligands as 4-connected nodes.

机译：配位聚合物，[MnL0.5（H 2 O）（PhO）]（N）（H4L = L，1'：4'，L“ - 苯基-2”，4,4“，5'-四羧酸，Phen = 1,10-菲咯啉）在单晶X射线衍射中被合成和结构表征。复合物结晶在三级液中。 GR。 p l = 1_ z = 2.中央苯基中的两种羧酸氧原子，来自两个mu（6）-14-配体的双桥两毫升（ii）离子形成二核mn-2（OCOO-）（2）单位。每个核核mn-2（OCOO - ）（2）单元链接四个L4-配体，每个L4-配体桥梁四个二核MN-2（OCOO - ）（2）单位，以产生2D协调网络，可以合理化为a 二进制（4,4）拓扑网络通过考虑硫赤MN-2（OCOO - ）（2）单位和L4-配体作为4个连接的节点。

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《Crystallography reports》 |2018年第3期|共4页
作者
Yin Xiu-Ju; Fu Yong;
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Hechi Univ Coll Chem &

Biol Engn Yizhou Guangxi Peoples R China;

Res Acad Jiangsu Hansoh Pharmaceut Grp Co Ltd Dongjin Rd Huaguoshan Ave Lianyungang 222069 Jiangsu Peoples R China;

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正文语种 eng
中图分类晶体学;
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机译：基于1,1'：4'，1“ - 替苯基-2”，4,4“，5' - 1-羧酸盐的二维配位聚合物
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A Two-Dimensional Coordination Polymer Based on 1,1 ':4 ', 1'-Terphenyl-2 ',4,4',5 '-tetracarboxylate

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