A Two-Fold Interpenetrating Porous Metal-Organic Framework with a Large Solvent-Accessible Volume: Gas Sorption and Luminescent Properties

Gong Yun-Nan; Xie Yong-Rong; Zhong Di-Chang; Du Zi-Yi; Lu Tong-Bu

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A Two-Fold Interpenetrating Porous Metal-Organic Framework with a Large Solvent-Accessible Volume: Gas Sorption and Luminescent Properties

机译：具有大量溶剂可及体积的两重互穿多孔金属有机骨架：气体吸附和发光特性

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A luminescent porous metal-organic frame-work based on pi-electron-rich tricarboxylate has been solvothermally prepared and characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analyses, and single-crystal X-ray diffraction analysis. This compound is a 2-fold interpenetrating framework with a large solvent-accessible volume and exhibits gas sorption behaviors for N-2, H-2, and CO2 gases and relatively strong interactions between CO2 and the framework. Furthermore, it also shows interesting guest-responsive luminescent changes toward different solvent molecules.

机译：溶剂热法制备了基于富π电子的三羧酸盐的发光多孔金属有机骨架，并通过傅里叶变换红外光谱，热重分析，元素分析和单晶X射线衍射分析对其进行了表征。该化合物是2互穿骨架，具有大的溶剂可及体积，并且对N-2，H-2和CO2气体表现出气体吸附行为，并且在CO2与骨架之间具有相对较强的相互作用。此外，它还显示出有趣的对不同溶剂分子的客体响应发光变化。

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《Crystal growth & design》 |2015年第7期|共4页
作者
Gong Yun-Nan; Xie Yong-Rong; Zhong Di-Chang; Du Zi-Yi; Lu Tong-Bu;
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正文语种 eng
中图分类晶体学;
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1. A Two-Fold Interpenetrating Porous Metal-Organic Framework with a Large Solvent-Accessible Volume: Gas Sorption and Luminescent Properties [J] . Gong Yun-Nan, Xie Yong-Rong, Zhong Di-Chang, Crystal growth & design . 2015,第7期

机译：具有大量溶剂可及体积的两重互穿多孔金属有机骨架：气体吸附和发光特性
2. Porous Metal-Organic Frameworks Containing Alkali-Bridged Two-Fold Interpenetration: Synthesis, Gas Adsorption, and Fluorescence Properties [J] . Zou RQ, Abdel-Fattah AI, Xu HW, Crystal growth & design . 2010,第3期

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4. TUNING THE STRUCTURE AND GAS SORPTION PROPERTIES OF METAL-ORGANIC FRAMEWORKS FOR HYDROGEN AND METHANE STORAGE [C] . Farshid Ramezanipour, Miguel Gonzalez, Jeffrey R. Long ACS National Meeting Exposition . 2014

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5. Design, synthesis, characterization, and sorption properties of metal-organic frameworks and polyhedra based on [iron(3)oxide(R dioxide)(6)L(3)](0/+) clusters. [D] . Sudik, Andrea C. 2005

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6. Metal-Organic Frameworks to Metal/Metal Oxide Embedded Carbon Matrix: Synthesis Characterization and Gas Sorption Properties [O] . Jiun-Jen Chen, Ya-Ting Chen, Duraisamy Senthil Raja, 2015

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A Two-Fold Interpenetrating Porous Metal-Organic Framework with a Large Solvent-Accessible Volume: Gas Sorption and Luminescent Properties

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