Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability

Ren P; Shi W; Cheng P

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Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability

机译：具有高热稳定性的三维3d-3d和3d-4f杂金属配位聚合物的合成与表征

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Using 1,2-bis(4-pyridyl)ethane (bpe) and benzene-1,3-biscarboxylic acid (H-2-bba) as ligands, two novel heterometallic three-dimensional coordination polymers {[Zn3Mn1.5(bpe)(bba)(4)(Hbba)]center dot bpe)(n) (Mn-Zn) and {[Zn2Pr(bpe)(bba)(3)(Hbba)]center dot H2O)(n) (Pr-Zn) were isolated under hydrothermal conditions. Both complexes are constructed via 3d-3d and 3d-4f clusters as secondary building units, respectively, which represent the first template synthesis for 3D heterometallic MOFs.

机译：使用1,2-双（4-吡啶基）乙烷（bpe）和苯-1,3-双羧酸（H-2-bba）作为配体，制备了两种新型的杂金属三维配位聚合物{[Zn3Mn1.5（bpe）（bba）（4）（Hbba）]中心点bpe）（n）（Mn-Zn）和{[Zn2Pr（bpe）（bba）（3）（Hbba）]中心点H2O）（n）（Pr-Zn在水热条件下分离。两种配合物分别通过3d-3d和3d-4f簇作为二级构建单元构建，代表了3D异金属MOF的第一个模板合成。

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《Crystal growth & design》 |2008年第4期|共3页
作者
Ren P; Shi W; Cheng P;
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正文语种 eng
中图分类晶体学;
关键词
FRAMEWORKS; DESIGN; FERROMAGNETISM; ADSORPTION; STORAGE; SOLIDS; SIZE; MOFS;

机译：框架;设计;铁磁性;吸附;存储;固体;尺寸;MOFS;

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1. Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability [J] . Ren P, Shi W, Cheng P Crystal growth & design . 2008,第4期

机译：具有高热稳定性的三维3d-3d和3d-4f杂金属配位聚合物的合成与表征
2. Hydrothermal Synthesis, Crystal Structure and Characterization of a Microporous 3D Pillared-Layer 3d-4f Copper-Holmium Heterometallic Coordination Polymer [J] . Le-Qing Fan, Ji-Huai Wu, Yun-Fang Huang Bulletin of the Korean Chemical Society . 2014,第6期

机译：微孔3D夹层3d-4f铜-He杂金属配位聚合物的水热合成，晶体结构和表征
3. A series of three-dimensional 3d-4f cyanide heterometallic coordination polymers: synthesis, crystal structure, photoluminescent and magnetic properties [J] . Ying-Zhao Ma, Li-Min Zhang, Guo Peng CrystEngComm . 2014,第4期

机译：一系列三维3d-4f氰化物杂金属配位聚合物：合成，晶体结构，光致发光和磁性
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸苯酯为桥联配体的水热合成和表征：{Cu（phen）（μ4-bta）1/2·（H2O）} n（phen = 1,10-菲咯啉
5. Syntheses and characterization of homo- and heterometallic tert-butoxides/cyclopentadienides of group 4/14 metals and mixed ligand (tert-butoxides/cyclopentadienides) coordination polymers of group 1/14 metals [D] . Njua, Edmond Yong 2012

机译：4/14族金属的均金属和杂金属叔丁氧化物/环戊二烯与1/14族金属的混合配体（叔丁氧化物/环戊二烯）配位聚合物的合成与表征
6. Ionothermal Synthesis of Cadmium Coordination Polymers: Ionic Liquid Effects on the Synthesis Structural and Thermal Characterization [O] . Iñigo PerezF, Edurne S. Larrea, Begoña Bazán, 2019

机译：离子热合成镉配位聚合物：离子液体对合成结构和热表征的影响
7. Hydrothermal Synthesis, Crystal Structure and Characterization of a Microporous 3D Pillared-Layer 3d-4f Copper-Holmium Heterometallic Coordination Polymer [O] . Le-Qing Fan, Ji-Huai Wu, Yun-Fang Huang, 2014

机译：微孔3D柱层3D-4F铜 - 钬杂体配位聚合物的水热合成，晶体结构及其表征

Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability

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