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Growth of highly compressed and regular coiled carbon nanotubes by a spray-pyrolysis method

机译:喷雾热解法生长高度压缩且规则卷曲的碳纳米管

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Cupric acetate dissolved in ethanol was applied for the first time for synthesizing highly compressed and regular coiled carbon nanotubes (CCNTs). This was done by spray pyrolysis of the ethanol solution intermittently supplied into the reaction zone at 850 degrees C. The grown CCNTs were in high purity and high yield and consisted of well-defined graphitic layers and fine regular coils. All the CCNTs had a uniform shape with a sharp radius Of Curvature and a small coil pitch. The growth of such CCNTs may be related to the use of Cu as the catalyst and the periodical supply of the carbon source. That is, such catalyst particles may be in a melted or semimelted state and susceptible to the fluctuation of growth conditions at the experimental temperature. Because of the simplicity of the present technique, it may be suitable for large-quantity production of CCNTs to be used in wide areas.
机译:首次将溶解在乙醇中的乙酸铜用于合成高度压缩的规则碳纳米管(CCNT)。这是通过在850摄氏度下间歇地将乙醇溶液进行喷雾热解而完成的。生长的CCNT具有高纯度和高收率,并且由定义明确的石墨层和精细规则的线圈组成。所有的CCNT均具有均匀的形状,具有陡峭的曲率半径和小的线圈间距。这种CCNT的生长可能与使用Cu作为催化剂和碳源的定期供应有关。即,这样的催化剂颗粒可以处于熔融或半熔融状态,并且易于在实验温度下生长条件的波动。由于本技术的简单性,它可​​能适合于大面积生产的CCNT,以在广阔的领域中使用。

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