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Ultrasonic field induced chiral symmetry breaking of NaClO3 crystallization

机译:超声场诱导NaClO3结晶手性对称断裂

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摘要

It is found that chiral symmetry breaking can be achieved in NaClO3 crystallization under an ultrasonic field, with a large crystal enantiomeric excess (mean values > 0.967) in almost every crystallization, and complete chiral symmetry breaking can be realized by seed inducing under the ultrasonic field. The chirality propagating process through secondary nucleation originating from an initial nucleus or a seed can be directly observed, and this large enantiomeric excess can be explained through secondary nucleation induced by the cavitation of the ultrasonic field and a recycling process.
机译:发现在超声场下NaClO3结晶中可以达到手性对称性破坏,几乎每个结晶中都有较大的晶体对映体过量(均值> 0.967),并且在超声场下通过诱导晶种可以实现完全的手性对称性破坏。 。可以直接观察到通过起源于初始核或种子的二次成核的手性传播过程,并且这种大的对映体过量可以通过超声场的空化和再循环过程引起的二次成核来解释。

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