Sodium-Mediated Self-Assembly: Three Novel 2D Coordination Aggregates of 1,4,7-Triazacyclononane-N,N ',N ''-tripropionate

Chen GJ; Gao FX; Huang FP; Tian JL; Gu W; Liu X; Yan SP; Liao DZ

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Sodium-Mediated Self-Assembly: Three Novel 2D Coordination Aggregates of 1,4,7-Triazacyclononane-N,N ',N ''-tripropionate

机译：钠介导的自组装：1,4,7-三氮杂环壬烷-N，N'，N''-三丙酸酯的三种新型二维配位聚集体

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Three types of Na+-mediated hybrid transition metal-alkali complexes possessing special architectures with molecular formulas of [Na(H2O)(3)(mu-L)Mn](MnL)(ClO4)(3)center dot 9H(2)O center dot(2H(3)O(+)) (2), [Na5Mn2(mu-L)(2)](ClO4)(5)(H2O)(6) (3) and [Na(NiL)(2)](ClO4)(2)center dot 5H(2)O(3H(3)O(+)) (4) (H3L = 1,4,7-triazacyclononane-N,N',N ''-tripropionic acid) were self-assembled from a reaction system containing transition metal, alkali metal and H3L, and were isolated under different crystallization conditions. In these complexes, [ML] units were connected by Na+ ions to form varied 2D layer structures. Na+ ions act as templates for inducing the organization of [ML] moieties into respective special architectures in different fashions. As a comparison, a mononuclear complex [MnL](2)[Mn(H2O)(6)](ClO4)(3)center dot 8H(2)O (1) has been isolated without Na+ ions in the reaction system. This fact proved that sodium ions play a vital role in the assembly procedure. These four complexes have been characterized by elemental analysis, IR, UV spectroscopy and single-crystal X-ray diffraction.

机译：三种具有特殊结构的Na +介导的杂化过渡金属-碱金属配合物，其分子式为[Na（H2O）（3）（mu-L）Mn]（MnL）（ClO4）（3）中心点9H（2）O中心点（2H（3）O（+））（2），[Na5Mn2（mu-L）（2）]（ClO4）（5）（H2O）（6）（3）和[Na（NiL）（2 ）]（ClO4）（2）中心点5H（2）O（3H（3）O（+））（4）（H3L = 1,4,7-三氮杂环壬烷-N，N'，N''-三丙酸）由含有过渡金属，碱金属和H3L的反应系统自组装，并在不同的结晶条件下进行分离。在这些络合物中，[ML]单元通过Na +离子连接以形成变化的2D层结构。 Na +离子充当模板，以不同的方式将[ML]部分的组织诱导为各自的特殊结构。作为比较，已分离出反应体系中不含Na +离子的单核络合物[MnL]（2）[Mn（H2O）（6）]（ClO4）（3）中心点8H（2）O（1）。这一事实证明，钠离子在组装过程中起着至关重要的作用。这四种复合物已通过元素分析，红外，紫外光谱和单晶X射线衍射进行了表征。

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《Crystal growth & design》 |2009年第6期|共6页
作者
Chen GJ; Gao FX; Huang FP; Tian JL; Gu W; Liu X; Yan SP; Liao DZ;
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正文语种 eng
中图分类晶体学;
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MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; METAL-IONS;

机译：磁性;晶体结构;金属离子;

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1. Sodium-Mediated Self-Assembly: Three Novel 2D Coordination Aggregates of 1,4,7-Triazacyclononane-N,N ',N ''-tripropionate [J] . Chen GJ, Gao FX, Huang FP, Crystal growth & design . 2009,第6期

机译：钠介导的自组装：1,4,7-三氮杂环壬烷-N，N'，N''-三丙酸酯的三种新型二维配位聚集体
2. 1,4,7-tris-(4-pyridylmethyl)-1,4,7-triazacyclononane, a new target molecule for the self-assembly of 3-D cage molecules [J] . Plasseraud L., Saalfrank RW. Phosphorus, Sulfur, and Silicon and the Related Elements . 2001,第0期

机译：1,4,7-三（4-吡啶甲基）-1,4,7-三氮杂环壬烷，3-D笼状分子自组装的新目标分子
3. 1,4,7-tris-(4-pyridylmethyl)-1,4,7-triazacyclononane, a new target molecule for the self-assembly of 3-D cage molecules [J] . Plasseraud L., Saalfrank RW. Phosphorus, Sulfur, and Silicon and the Related Elements . 2001,第0期

机译：1,4,7-三（4-吡啶甲基）-1,4,7-三氮杂环壬烷，3-D笼状分子自组装的新目标分子
4. Stabilization of aqueous first-row transition metal-hydroxo clustersby coordination with 1,4,7-triazacyclononane complexes [C] . Sugiarto, Shota Kazakami, Yuya Imai 日本化学会春季年会 . 2020

机译：用1,4,7-三氮杂环烷复合物配位稳定水性第一行过渡金属 - 羟基簇区
5. Physical and chemical investigations of iron complexes with 1,4,7-trimethyl-1,4,7-triazacyclononane and [2.2.2.2.3]adamanzane. [D] . Blakesley, David William. 2001

机译：与1,4,7-三甲基-1,4,7-三氮杂环壬烷和[2.2.2.2.3]金刚烷的铁配合物的物理和化学研究。
6. The Zn(II)-1,4,7-Trimethyl-1,4,7-Triazacyclononane Complex: A Monometallic Catalyst Active in Two Protonation States [O] . Marta Diez-Castellnou, Giovanni Salassa, Fabrizio Mancin, 1970

机译：Zn（II）-1,4,7-三甲基-1,4,7-三氮杂环壬烷络合物：在两个质子化状态下具有活性的单金属催化剂
7. Synthesis, characterization, and acidity of ruthenium dihydrogen complexes with 1,4,7-triazacyclononane, 1,4,7-trimethyl-1,4,7-triazacyclononane, and hydrotris (pyrazolyl)borato ligands [O] . Ng SM, Fang YQ, Lau CP, 1998

机译：具有1,4,7-三氮杂环壬烷，1,4,7-三甲基-1,4,7-三氮杂环壬烷和氢三（吡唑基）硼酸酯配体的钌二氢配合物的合成，表征和酸度

Sodium-Mediated Self-Assembly: Three Novel 2D Coordination Aggregates of 1,4,7-Triazacyclononane-N,N ',N ''-tripropionate

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