Two porous zinc coordination polymers with (10,3) topological features based on a N-centered tripodal ligand and the conversion of a (10,3)-d Subnet to a (10,3)-a Subnet

Yao X.-Q.; Zhang M.-D.; Hu J.-S.; Li Y.-Z.; Guo Z.-J.; Zheng H.-G.

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Two porous zinc coordination polymers with (10,3) topological features based on a N-centered tripodal ligand and the conversion of a (10,3)-d Subnet to a (10,3)-a Subnet

机译：两种具有（10,3）拓扑特征的多孔锌配位聚合物，基于N中心三脚架配体，并将（10,3）-d子网转换为（10,3）-a子网

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Two porous (3,4)-connected zinc coordination polymers, {[Zn(TIPA)(mal) _(1/2)](NO_3)?_3H_2O}_n (1) and {[Zn(TIPA)(glu)_(1/2)](NO_3)?H_2O}_n (2) (mal = malonic acid, glu = glutaric acid, TIPA = tris(4-(1H-imidazol-1-yl) phenyl)amine) have been hydrothermally synthesized and characterized. Complex 1 crystallizes in the orthorhombic space group Pnna (No. 52) containing an unusual 3D subnet with (10,3)-d topology and left- and right-handed helical channels. Complex 2 crystallizes in the orthorhombic chiral space group P222_1 (No. 17) containing an unusual 3D chiral subnet with (10,3)-a topology and 4-fold right-handed helical channels. The conversion of achiral complex 1 with a (10,3)-d (utp) achiral subnet to chiral complex 2 with a (10,3)-a (srs) chiral subnet has been successfully induced by increasing the length of ditopic aliphatic dicarboxylic acid. Second harmonic generation (SHG) measurement was performed on complex 2 revealing that 2 has a strong SHG response, and the SHG efficiency is approximately 0.8 times that of urea (ca. 8 times that of KDP). In addition, photoluminescence and thermogravimetric analysis were also performed on 1 and 2.

机译：两种多孔（3,4）连接的锌配位聚合物，{[Zn（TIPA）（mal）_（1/2）]（NO_3）？_ 3H_2O} _n（1）和{[Zn（TIPA）（glu）_ （1/2）]（NO_3）→H_2O} _n（2）（mal =丙二酸，glu =戊二酸，TIPA =三（4-（1H-咪唑-1-基）苯基）胺）已经水热合成。和特点。配合物1在正交空间群Pnna（第52号）中结晶，该群包含具有（10,3）-d拓扑结构以及左手和右手螺旋形通道的不寻常3D子网。配合物2在正交晶体手性空间群P222_1（第17号）中结晶，该群包含具有（10,3）-a拓扑结构和4倍右旋螺旋通道的不寻常3D手性子网。通过增加对位脂肪族二羧酸的长度，成功地诱导了具有（10,3）-d（utp）非手性子网的非手性复合物1向具有（10,3）-a（srs）手性子网的手性复合物2的转化。酸。对复合物2进行了二次谐波生成（SHG）测量，发现2具有较强的SHG响应，SHG效率约为尿素的0.8倍（约为KDP的8倍）。此外，还对1和2进行了光致发光和热重分析。

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《Crystal growth & design》 |2011年第7期|共6页
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Yao X.-Q.; Zhang M.-D.; Hu J.-S.; Li Y.-Z.; Guo Z.-J.; Zheng H.-G.;
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1. Two porous zinc coordination polymers with (10,3) topological features based on a N-centered tripodal ligand and the conversion of a (10,3)-d Subnet to a (10,3)-a Subnet [J] . Yao X.-Q., Zhang M.-D., Hu J.-S., Crystal growth & design . 2011,第7期

机译：两种具有（10,3）拓扑特征的多孔锌配位聚合物，基于N中心三脚架配体，并将（10,3）-d子网转换为（10,3）-a子网
2. Novel noncentrosymmetric zinc coordination polymer containing an unusual zinc carboxylate-sulfonate substructure with a (10,3)-d topology and its second-harmonic-generation properties [J] . Liu Q.-Y., Wang Y.-L., Shan Z.-M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2010,第18期

机译：新型非中心对称锌配位聚合物，其包含具有（10,3）-d拓扑的不寻常的羧酸锌磺酸盐亚结构及其二次谐波生成特性
3. Erratum: Novel noncentrosymmetric zinc coordination polymer containing an unusual zinc carboxylate-sulfonate substructure with a (10,3)-d topology and its second-harmonic-generation properties (Inorganic Chemistry (2010) 49 (8191)) [J] . Liu Q.-Y., Wang Y.-L., Shan Z.-M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2010,第21期

机译：勘误表：新型非中心对称锌配位聚合物，其包含具有（10,3）-d拓扑结构的不寻常的羧酸锌磺酸盐亚结构及其二次谐波生成特性（无机化学（2010）49（8191））
4. Storage and dynamics of CO2 into porous coordination polymer controlled by ligand dynamics [C] . Munehiro Inukai, Masanori Tamura, Satoshi Horike 日本化学会春季年会講演予稿集 . 2018

机译：用配体动力学控制CO2进入多孔配位聚合物的储存和动力学
5. Synthesis and coordination chemistry of tripodal thioether-pyrazole ligands and their application to modeling reactivity of zinc thiolate enzymes. [D] . Chiou, Show-Jen. 2004

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6. Coordination of 3‐Methylindole‐Based Tripodal Tetraphosphine Ligands to Iron(+II) Cobalt(+II) and Nickel(+II) and Investigations of their Subsequent Two‐Electron Reduction [O] . Fenna F. van de Watering, Wowa Stroek, Jarl Ivar van der Vlugt, -1

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机译：非典型网络：使用非对称柔性配体和AG（I）作为三个连接节点的非接触（10,3）-D网

Two porous zinc coordination polymers with (10,3) topological features based on a N-centered tripodal ligand and the conversion of a (10,3)-d Subnet to a (10,3)-a Subnet

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