Metal-organic frameworks with achiral/monochiral nano-channels

Yi X.-Y.; Fang H.-C.; Gu Z.-G.; Zhou Z.-Y.; Cai Y.-P.; Tian J.; Thallapally P.K.

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Metal-organic frameworks with achiral/monochiral nano-channels

机译：具有非手性/单手性纳米通道的金属有机骨架

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Three pH/temperature-dependent 2D MOFs containing 1D nanotubular meso-helical chains were firstly synthesized from multidentate 2,4-H _2bpdc. Crystal structure analysis shows that 2 and 3 are monochiral and the resultant crystals were not racemic as evidenced by the observation of strong signals in vibrational circular dichroism (VCD) and circular dichroism (CD) spectra.

机译：首先从多齿2,4-H _2bpdc合成了三个包含1D纳米管中螺旋链的pH /温度依赖性2D MOF。晶体结构分析表明2和3是单手性的，并且通过在振动圆二色性（VCD）和圆二色性（CD）光谱中观察到强信号可以证明所得晶体不是外消旋的。

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《Crystal growth & design》 |2011年第7期|共5页
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Yi X.-Y.; Fang H.-C.; Gu Z.-G.; Zhou Z.-Y.; Cai Y.-P.; Tian J.; Thallapally P.K.;
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正文语种 eng
中图分类晶体学;
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专利

1. Metal-organic frameworks with achiral/monochiral nano-channels [J] . Yi X.-Y., Fang H.-C., Gu Z.-G., Crystal growth & design . 2011,第7期

机译：具有非手性/单手性纳米通道的金属有机骨架
2. Chiral Reticular Self-Assembly of Achiral AIEgen into Optically Pure Metal-Organic Frameworks (MOFs) with Dual Mechano-Switchable Circularly Polarized Luminescence [J] . Shang Weili, Zhu Xuefeng, Liang Tongling, Angewandte Chemie . 2020,第31期

机译：具有双重机械可切换圆极化发光的双层机械纯金属 - 有机框架（MOFS）的手性网状自组装
3. Spontaneous Resolution and Structure Transformation of Ni-II Metal-Organic Frameworks from an Achiral Precursor [J] . Tao Ye, Yang Cheng, Fang Han, Nature reviews Cancer . 2019,第6期

机译：从成立前体的Ni-II金属 - 有机骨架的自发分辨率和结构转化
4. Zeolites embrace metal-organic frameworks: building block approach to the design and synthesis of zeolite-like metal-organic frameworks (ZMOFs) [C] . Zehong Zhang, Fuyuan Liu, Yunwen Wang, 40th Anniversary of International Zeolite Conference;International Zeolite Conference . 2007

机译：沸石包含金属有机骨架：构造和合成类沸石金属有机骨架（ZMOF）的基础方法
5. Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation [D] . Phan, Anh Thi Phuong 2011

机译：金属有机骨架，包括高通量合成沸石咪唑酸酯骨架，及其在二氧化碳捕获，储存和甲烷活化催化剂中的应用
6. High-internal-phase emulsions stabilized by metal-organic frameworks and derivation of ultralight metal-organic aerogels [O] . Bingxing Zhang, Jianling Zhang, Chengcheng Liu, -1

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7. Chiral magnetic metal-organic frameworks of Mn-II with achiral tetrazolate-based ligands by spontaneous resolution [O] . Tong X. L., Hu T. L., Zhao J. P., 2010

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Metal-organic frameworks with achiral/monochiral nano-channels

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