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Noncovalent syntheses of supramolecular organo gelators

机译:超分子有机胶凝剂的非共价合成

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摘要

Four new organo gelators, namely, dicyclohexylammonium hydrogen cyclobutane-1,1-dicarboxylate (1), dicyclohexylammonium cyclobutane-1,1-dicarboxylate (2), dibenzylammonium hydrogen cyclobutane-1,1-dicarboxylate (3), and dibenzylammonium cyclobutane-1,1-dicarboxylate (4), have been noncovalently synthesized. Single-crystal structures of all the gelators were determined to make an attempt to correlate their structure with their properties (gelation). The results support the conclusion that a one-dimensional hydrogen-bonded network in the crystal structure appears to be one of the prerequisites for gelation behavior.
机译:四种新的有机胶凝剂,即环丁烷-1,1-二羧酸二环己基铵(1),环丁烷-1,1-二羧酸二环己基铵(2),环丁烷-1,1-二羧酸二苄基铵氢(1)和环丁烷二苄基铵(1) ,1-二羧酸酯(4)已经非共价合成。确定所有胶凝剂的单晶结构,以尝试使它们的结构与其特性(胶凝)相关联。结果支持这样的结论:晶体结构中的一维氢键网络似乎是凝胶化行为的前提之一。

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