Close packing in crystals of cyanophenylene/thienylene derivatives

Porzio W; Destri S; Pasini M; Rapallo A; Giovanella U

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Close packing in crystals of cyanophenylene/thienylene derivatives

机译：紧密堆积在氰基亚苯基/亚噻吩衍生物的晶体中

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摘要

A new molecule, designed as a potential active material in field effect transistor (FET) devices and constituted by p-cyanophenylene and - thienylene residues, has been synthesized and characterized by electrochemical, photophysical, and structural points of view. Its crystal structure, derived from powder XRD data, displays higher close packing as compared with molecular crystals constituted by similar residues. The crystallization aptness has been demonstrated by growing solid films, from 15 nm to 2 Am thick, using high vacuum depositions, casting, and spin coating techniques. AFM investigation shows well formed needles, univocally oriented with respect to the substrate. The HOMO/LUMO levels, matching the electrode working function, the film orientation, and the close packing, suggest its promising use as an active layer in FET devices.

机译：已经合成了一种新分子，该分子被设计为场效应晶体管（FET）器件中的潜在活性材料，并由对氰基亚苯基和亚噻吩基残基组成，并从电化学，光物理和结构的角度对其进行了表征。从粉末XRD数据得出的晶体结构与由相似残基组成的分子晶体相比，具有更高的紧密堆积。通过使用高真空沉积，流延和旋涂技术，从15 nm到2 Am厚的固体膜生长，证明了晶体的适用性。原子力显微镜调查显示，针头相对于基材具有唯一取向的结构良好的针头。与电极工作功能，薄膜取向和紧密堆积相匹配的HOMO / LUMO含量表明其有望用作FET器件中的有源层。

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《Crystal growth & design》 |2006年第6期|共7页
作者
Porzio W; Destri S; Pasini M; Rapallo A; Giovanella U;
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正文语种 eng
中图分类晶体学;
关键词
FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; POWDER DIFFRACTION DATA; AMBIPOLAR TRANSPORT; SURFACE-AREA; VOLUMES; OLIGOTHIOPHENES; QUINODIMETHANE; SEMICONDUCTORS; TERTHIOPHENE;

机译：场效应晶体管;薄膜晶体管;粉末衍射数据;非球面传输;表面区域;体积;低硫苯;喹二甲烷;半导电性;三苯并菲;

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专利

1. Close packing in crystals of cyanophenylene/thienylene derivatives [J] . Porzio W, Destri S, Pasini M, Crystal growth & design . 2006,第6期

机译：紧密堆积在氰基亚苯基/亚噻吩衍生物的晶体中
2. Cocrystallization of a tripyridyl donor with perfluorinated lodobenzene derivatives: Formation of different N center dot center dot center dot I halogen bonds determining network vs plain packing crystals [J] . Vartanian M, Lucassen ACB, Shimon LJW, Crystal growth & design . 2008,第3期

机译：三芳基供体与全氟碘苯衍生物的共结晶：形成不同N中心点中心点中心点I卤素键的形成决定了网络与纯堆积晶体
3. Strong Coupling of Light with Extremely Thin Non-Close-Packing Colloidal Crystals: Experimental and Theoretical Studies [J] . HUANG Zhong, DONG Wen 中国物理快报：英文版 . 2013,第004期

机译：光与极薄的非紧密堆积胶体晶体的强耦合：实验和理论研究
4. Two-dimensional photonic crystals fabrication and close-packing by electron-beam lithography [C] . Utkin Dmitry E., Nasimov Dmitry A., Latyshev Alexander V. 2012 13th International Conference and Seminar of Young Specialists on Micro/Nanotechnologies and Electron Devices. . 2012

机译：二维光子晶体的电子束光刻制备与密排
5. Altering the Crystal Packing of Boronsubphthalocyanine Derivatives through Molecular Engineering. [D] . Paton, Andrew Simon. 2013

机译：通过分子工程改变硼亚酞菁衍生物的晶体堆积。
6. Icosahedral and decagonal quasicrystals of intermetallic compounds are multiple twins of cubic or orthorhombic crystals composed of very large atomic complexes with icosahedral point-group symmetry in cubic close packing or body-centered packing: Structure of decagonal Al6Pd [O] . Linus Pauling 1989

机译：金属间化合物的二十面体和十面体准晶体是立方或正交晶体的多个孪晶由立方密堆积或体心堆积中具有二十面体点群对称的非常大的原子络合物组成：十方Al6Pd结构
7. Icosahedral and decagonal quasicrystals of intermetallic compounds are multiple twins of cubic or orthorhombic crystals composed of very large atomic complexes with icosahedral point-group symmetry in cubic close packing or body-centered packing: Structure of decagonal Al6Pd [O] . Pauling, Linus 1989

机译：金属间化合物的二十面体和十面体准晶体是立方或正交晶体的多个孪晶，由立方密堆积或体心堆积中具有二十面体点群对称的非常大的原子络合物组成：十方Al6Pd结构
8. Topological Close Packing in Structurally Complex Intermetallics (Crystalline, Quasicrystalline and Noncrystalline) [R] . Ranganathan, S. 2006

机译：结构复杂金属间化合物（晶体，准晶体和非晶体）中的拓扑密堆积

Close packing in crystals of cyanophenylene/thienylene derivatives

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