Interplay of hydrogen bonds in assembling (4,4)-coordination networks: Transformations from open to interpenetrated networks via anion exchange

Sarkar M; Biradha K

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Interplay of hydrogen bonds in assembling (4,4)-coordination networks: Transformations from open to interpenetrated networks via anion exchange

机译：组装（4,4）-配位网络中氢键的相互作用：通过阴离子交换从开放网络转变为互穿网络

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Open (4,4)-coordination networks were shown to assemble via N-H center dot center dot center dot O hydrogen bonds in two different ways: the usual offset packing via beta-sheet hydrogen bonds and an unprecedented trigonal packing. Both of the structures have continuous channels that are occupied by guest molecules ( nitrobenzene or EtOH and H2O) which account for 37% or 28% of the crystal volume. Interestingly, these complexes have shown an ability to exchange ClO4- with PF6- ions and transform into the doubly interpenetrated varieties.

机译：开放的（4,4）配位网络显示通过N-H中心点中心点中心点O氢键以两种不同方式组装：通过β-折叠氢键的通常的偏移堆积和前所未有的三角堆积。两种结构均具有连续通道，该通道被客体分子（硝基苯或EtOH和H2O）占据，该客体占晶体体积的37％或28％。有趣的是，这些复合物已显示出将ClO4-与PF6-离子交换并转化为双互穿变体的能力。

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《Crystal growth & design》 |2006年第8期|共4页
作者
Sarkar M; Biradha K;
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原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
COORDINATION POLYMERS; CRYSTAL-STRUCTURES; FRAMEWORK; MOLECULES; CAVITIES; SOLIDS; DESIGN;

机译：配位聚合物;晶体结构;框架;分子;空穴;固体;设计;

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1. Interplay of hydrogen bonds in assembling (4,4)-coordination networks: Transformations from open to interpenetrated networks via anion exchange [J] . Sarkar M, Biradha K Crystal growth & design . 2006,第8期

机译：组装（4,4）-配位网络中氢键的相互作用：通过阴离子交换从开放网络转变为互穿网络
2. Two-dimensional coordination polymer with a non-interpenetrated (4,4) net showing anion exchange and structural transformation in single-crystal-to- single-crystal fashion [J] . Aijaz A., Lama P., Bharadwaj P.K. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2010,第13期

机译：具有非互穿（4,4）网的二维配位聚合物，以单晶至单晶方式显示阴离子交换和结构转变
3. Supramolecular networks through second-sphere coordination based on 1D metal-4,4′-dipyridyldisulfide coordination polymers and hydrogenfumarate or sulfonate anions [J] . Carballo R., Fernández-Hermida N., Lago A.B., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2012,第1期

机译：基于一维金属4,4'-二吡啶基二硫化物配位聚合物和富马酸氢盐或磺酸根阴离子的第二球配位的超分子网络
4. A New 2-D Coordination Polymer with Hydrogen Bonding Network Assembled by Yttrium(Ⅲ) and 4-Methyl-6-Hydroxypyrimidine:Y(H2O)8(C5H6N2O)2(NO3)3 [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：钇（Ⅲ）与4-甲基-6-羟基嘧啶组装的具有氢键网络的新型二维配位聚合物：Y（H2O）8（C5H6N2O）2（NO3）3
5. Replacing hydrogen bonds with coordinate covalent bonds in coordination networks. [D] . Rodger, Colin S. 2009

机译：在配位网络中用配位共价键取代氢键。
6. Synthesis and Characterization of Novel Anion Exchange Membranes Based on Semi-Interpenetrating Networks of Functionalized Polysulfone: Effect of Ionic Crosslinking [O] . Sydonne Swaby, Nieves Ureña, María Teresa Pérez-Prior, 2021

机译：基于半渗透性多砜网络的新型阴离子交换膜的合成与表征：离子交联的影响
7. Interplay of Hydrogen Bonds in Assembling (4, 4)-Coordination Networks: Transformations from Open to Interpenetrated Networks via Anion Exchange [O] . -1

机译：氢键在组装（4,4）的互补网络中的相互作用：通过阴离子交换从开放到互通网络的转换

Interplay of hydrogen bonds in assembling (4,4)-coordination networks: Transformations from open to interpenetrated networks via anion exchange

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