Syntheses, structures, and magnetic properties of two novel three-dimensional frameworks built from M4O4 cubanes and dicyanamide bridges

Lin ZD; Li ZF; Zhang HJ

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Syntheses, structures, and magnetic properties of two novel three-dimensional frameworks built from M4O4 cubanes and dicyanamide bridges

机译：由M4O4古巴人和双氰胺桥构建的两个新颖的三维骨架的合成，结构和磁性

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Two novel coordination polymers Ni-4(CH3O)(4)(CH3OH)(4)(dca)(4) (1) and Co-4(CH3O)(4)(CH3OH)(4)(dca)(4) (2) have been synthesized by solvethermal reaction. X-ray single-crystal analysis reveals that the two complexes are isostrutural and possess 3D frameworks that are built from the M4O4(M= Ni (1) and Co (2)) cubanelike building blocks linked by dicyanamide (dca) bridges. The temperature dependence of the magnetic susceptibility was measured and the DC experiment data were fitted using the Heisenberg spin Hamiltonian.

机译：两种新型配位聚合物Ni-4（CH3O）（4）（CH3OH）（4）（dca）（4）（1）和Co-4（CH3O）（4）（CH3OH）（4）（dca）（4）（2）已通过溶解热反应合成。 X射线单晶分析表明，这两个复合物是同构的，并具有3D框架，这些框架是由通过双氰胺（dca）桥连接的M4O4（M = Ni（1）和Co（2））古巴样结构单元构建的。测量了磁化率的温度依赖性，并使用海森堡自旋哈密顿量拟合了直流实验数据。

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《Crystal growth & design》 |2007年第4期|共3页
作者
Lin ZD; Li ZF; Zhang HJ;
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正文语种 eng
中图分类晶体学;
关键词
SINGLE-MOLECULE MAGNETS; CRYSTAL-STRUCTURE; GROUND-STATE; COMPLEX; CLUSTERS; EXCHANGE; SUSCEPTIBILITY; LIGANDS; NICKEL; ATOMS;

机译：单分子磁体;晶体结构;基态;复合体;团簇;交换;磁化率;配体;镍基;原子;

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1. Syntheses, structures, and magnetic properties of two novel three-dimensional frameworks built from M4O4 cubanes and dicyanamide bridges [J] . Lin ZD, Li ZF, Zhang HJ Crystal growth & design . 2007,第4期

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机译：用双氰胺的手性分层金属 - 有机骨架的晶体结构和磁性和铁电性能作为桥接配体

Syntheses, structures, and magnetic properties of two novel three-dimensional frameworks built from M4O4 cubanes and dicyanamide bridges

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