A Borromean Weave Coordination Polymer Sustained by Urea-Sulfate Hydrogen Bonding and Its Selective Anion Separation Properties

Adarsh NN; Dastidar P

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A Borromean Weave Coordination Polymer Sustained by Urea-Sulfate Hydrogen Bonding and Its Selective Anion Separation Properties

机译：尿素-硫酸氢键维持的硼烷配位聚合物及其选择性阴离子分离性能

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A 3-fold (2D -> 2D) (6,3) Borromean weave coordination polymer sustained by urea-sulfate hydrogen bonding is formed when N,N'-bis(3-pyridyl)-p-phenylenebisurea (L1) is reacted with ZnSO4 center dot 7H(2)O, whereas the corresponding bis-amide derivative N,N'-bis(3-pyridyl)terephthalamide (L2) gave a coordination polymer displaying a 2D corrugated sheet tinder the identical reaction conditions; sulfate anion can be selectively separated from a complex mixture of anions (sulfate, nitrate, perchlorate, and triflate) by in situ crystallization of these coordination polymers.

机译：当N，N'-双（3-吡啶基）-对亚苯基双脲（L1）与N，N'-双（3-吡啶基）-对苯撑双脲（L1）与ZnSO4中心点7H（2）O，而相应的双酰胺衍生物N，N'-双（3-吡啶基）对苯二甲酰胺（L2）得到的配位聚合物在相同的反应条件下显示出2D波纹片状接枝剂。通过这些配位聚合物的原位结晶，可以从复杂的阴离子混合物（硫酸根，硝酸根，高氯酸根和三氟甲磺酸根）中选择性分离硫酸根阴离子。

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《Crystal growth & design》 |2010年第2期|共5页
作者
Adarsh NN; Dastidar P;
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正文语种 eng
中图分类晶体学;
关键词
METAL-ORGANIC FRAMEWORKS; SHOWING STRUCTURAL DIVERSITY; LIGATING TOPOLOGIES; COUNTER-ANIONS; BINDING; NETWORKS; CRYSTAL; LIGANDS; RINGS; CRYSTALLIZATION;

机译：金属有机框架;结构多样性;连接拓扑;异阴离子;结合;网络;晶体;液体;环;结晶;

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1. A Borromean Weave Coordination Polymer Sustained by Urea-Sulfate Hydrogen Bonding and Its Selective Anion Separation Properties [J] . Adarsh NN, Dastidar P Crystal growth & design . 2010,第2期

机译：尿素-硫酸氢键维持的硼烷配位聚合物及其选择性阴离子分离性能
2. Selective separation of the sulfate anion by in situ crystallization of Cd~(II) coordination compounds derived from bis(pyridyl) ligands equipped with a urea/amide hydrogen-bonding backbone [J] . Banerjee S., Adarsh N.N., Dastidar P. European journal of inorganic chemistry . 2010,第24期

机译：通过原位结晶配备有脲/酰胺氢键主链的双（吡啶基）配体的Cd〜（II）配位化合物来选择性分离硫酸根阴离子
3. Role of Anions in the Formation of Multidimensional Coordination Polymers: Selective Separation of Anionic Toxic Dyes by 3D-Cationic Framework and Luminescent Properties [J] . Maity Kartik, Biradha Kumar Crystal growth & design . 2016,第5期

机译：阴离子在多维配位聚合物形成中的作用：通过3D阳离子骨架和发光特性选择性分离阴离子有毒染料
4. Hydrothermal Synthesis and Structural Characterization of a Novel 3-D Inorganic/organicHybrid Supermolecule Constructed from 1-D Coordination Polymers through Hydrogen Bonds [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：一维配位聚合物通过氢键构建的新型3-D无机/有机杂化超分子的水热合成和结构表征
5. Tetradipicolyamine-substituted resorc[4]arene cavitands: I. Anion binding and transition metal assembled coordination cages and nanoarchitectures. II. Polymer inclusion membranes applied to anion separations. [D] . Gardner, Joseph S. 2005

机译：Tetradipicolyamine取代的间苯二酚[4]芳烃空洞：I.阴离子结合和过渡金属组装的配位笼和纳米结构。二。适用于阴离子分离的聚合物包合物膜。
6. Different Supramolecular Coordination Polymers of NN-di(pyrazin-2-yl)-pyridine-26-diamineNi(II) with Anions and Solvent Molecules as a Result of Hydrogen Bonding [O] . Gene-Hsiang Lee, Hsin-Ta Wang 2007

机译：由于氢键作用NN-二（吡嗪-2-基）-吡啶-26-二胺 Ni（II）与阴离子和溶剂分子的超分子配位聚合物
7. Different Supramolecular Coordination Polymers of [N,N'-di(pyrazin-2-yl)-pyridine-2,6-diamine]Ni(II) with Anions and Solvent Molecules as a Result of Hydrogen Bonding [O] . Gene-Hsiang Lee, Hsin-Ta Wang 2007

机译：由于氢键作用，[N，N'-二（吡嗪-2-基）-吡啶-2,6-二胺] Ni（II）与阴离子和溶剂分子的超分子配位聚合物
8. Importance of weak hydrogen bonding C-H--donor and C-H--anion interactions in governing the structural properties of organic donors BEDT-TTF and BEDO-TTF and their charge-transfer salts. [R] . Whangbo, M. H., Jung, D., Ren, J., 1989

机译：弱氢键C-H - 供体和C-H - 阴离子相互作用在控制有机供体BEDT-TTF和BEDO-TTF及其电荷转移盐的结构性质中的重要性。

A Borromean Weave Coordination Polymer Sustained by Urea-Sulfate Hydrogen Bonding and Its Selective Anion Separation Properties

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