Photochromic Crystals:Toward an Understanding of Color Development in the Solid State

Janet L.Scott; Koichi Tanaka

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Photochromic Crystals:Toward an Understanding of Color Development in the Solid State

机译：光致变色晶体：对固态颜色发展的理解

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Intermolecular interactions between fluorene groups of propargylallenes define the solid state photochromic response of these materials.Examination of crystal structures of both photoresponsive and nonresponsive forms(including solvates)indicates that all compounds that are photochromic in the solid state exhibit donor/acceptor pi…pi interactions of fluorene aromatic systems that lead to infinite 1-D ribbons.Such interactions are absent in nonphotochromic crystalline forms.

机译：炔丙基烯丙基的芴基之间的分子间相互作用定义了这些材料的固态光致变色反应。对光敏和无敏形式的晶体结构（包括溶剂化物）的检查表明，所有处于固态的光致变色化合物均表现出供体/受体pi…pi相互作用导致无限一维带状的芴芳烃体系。非光致变色晶体形式不存在这种相互作用。

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《Crystal growth & design》 |2005年第3期|共5页
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Janet L.Scott; Koichi Tanaka;
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正文语种 eng
中图分类晶体学;
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3. Experimental investigation of the photochromic effect and two-color holographic recording in near-stoichiometric LiNbO_3:Fe:Mn crystals [J] . Liu Y., Zhou Y., Zhu M., Journal of nonlinear optical physics & materials . 2012,第4期

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Photochromic Crystals:Toward an Understanding of Color Development in the Solid State

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