Short S=O center dot center dot center dot C=O contacts associate diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate in their inclusion complexes

Manoj K; Sureshan KM; Gonnade RG; Bhadbhade MM; Shashidhar MS

首页> 外文期刊>Crystal growth & design >Short S=O center dot center dot center dot C=O contacts associate diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate in their inclusion complexes

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Short S=O center dot center dot center dot C=O contacts associate diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate in their inclusion complexes

机译：短S = O中心点中心点中心点C = O接触2,4（6）-二-O-苯甲酰基-6（4）-O-[（1S）-10-樟脑磺酰基]-肌醇的非对映异构体1,3,5-原甲酸酯的包合物

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摘要

Diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate are linked via short S=O&BULL;&BULL;&BULL; C=O contacts ranging from 2.890 to 3.140 &ANGS; (sum of the van der Waals radii of O and C atoms 3.22 &ANGS;) in all the inclusion complexes formed with organic guest solvents having a C2 symmetry. Although a search for S= O&BULL;&BULL;&BULL; C=O interactions in the CSD showed a sizable number of structures, this communication recognizes its significance for the first time in the formation of molecular assemblies. In all the crystals in the present study except the solvent-free form, the S=O bond points almost perpendicularly to the Csp2 atom of the C=O group. This was also the most frequently observed geometrical approach in CSD analysis. The solvent-free form shows dimer formation via C-H&BULL;&BULL;&BULL; O interaction, which has longer S=O&BULL;&BULL;&BULL; C=O contacts.

机译：2,4（6）-二-O-苯甲酰基-6（4）-O-[（1S）-10-樟脑磺酰基]-肌醇1,3,5-原甲酸酯的非对映异构体通过短S = O＆BULL连接; ＆BULL;＆BULL; C = O接触范围为2.890至3.140＆ANGS; （由O和C原子的范德华半径之和3.22＆ANGS;）与具有C2对称性的有机客体溶剂形成的所有包合物中。尽管搜索S = O＆BULL;＆BULL;＆BULL; CSD中的C = O相互作用显示出相当数量的结构，这种交流是第一次认识到其在分子组装体形成中的重要性。在本研究的所有晶体中，除无溶剂形式外，S = O键几乎垂直于C = O基团的Csp2原子。这也是CSD分析中最常观察到的几何方法。无溶剂形式显示出通过C-H＆BULL;＆BULL;＆BULL;形成二聚体。 O交互，它具有更长的S = O＆BULL;＆BULL;＆BULL; C = O触点。

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《Crystal growth & design》 |2005年第3期|共4页
作者
Manoj K; Sureshan KM; Gonnade RG; Bhadbhade MM; Shashidhar MS;
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正文语种 eng
中图分类晶体学;
关键词
MYO-INOSITOL; POLYMORPH;

机译：肌醇;聚甲醛;

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1. Short S=O center dot center dot center dot C=O contacts associate diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate in their inclusion complexes [J] . Manoj K, Sureshan KM, Gonnade RG, Crystal growth & design . 2005,第3期

机译：短S = O中心点中心点中心点C = O接触2,4（6）-二-O-苯甲酰基-6（4）-O-[（1S）-10-樟脑磺酰基]-肌醇的非对映异构体1,3,5-原甲酸酯的包合物
2. Subtle crossover from C-H center dot center dot center dot O to S=O center dot center dot center dot C=O short contacts in the association of diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate upon f [J] . Manoj K, Gonnade RG, Bhadbhade MM, Crystal growth & design . 2006,第6期

机译：从CH中心点中心点中心点O到S = O中心点中心点中心点C = O的细微交叉在2,4（6）-di-O-苯甲酰基-6（4）-的非对映体缔合中O-[（1S）-10-樟脑磺酰基]-肌醇1,3,5-原甲酸酯
3. Short S=O…C=O Contacts Associate Diastereomers of 2,4(6)-Di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-Orthoformate in Their Inclusion Complexes [J] . K.Manoj, Kana M.Sureshan, Rajesh G.Gonnade Crystal growth & design . 2005,第3期

机译：短S = O…C = O接触2,4（6）-Di-O-苯甲酰基-6（4）-O-[（1S）-10-樟脑磺酰基]-肌醇1,3,5的非对映异构体-邻甲酸酯在其包合物中
4. Comparative investigation of quantum-dot-like localization centers in InGaN quantum well and quantum dot structures [C] . K. Sebald, H. Lohmeyer, J. Gutowski, Symposium on GaN, AIN, InN and Related Materials . 2006

机译：IngaN量子阱和量子点结构中量子点状定位中心的比较研究
5. Low rate of non-compliance to antituberculous therapy under the banner of directly observed treatment short course (DOTS) strategy and well organized retrieval system: a call for implementation of this strategy at all DOTS centers in Saudi Arabia [O] . Liaqat Ali Chaudhry, Jaffar Al-Tawfiq, Ebtesam Ba-Essa, 2015

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6. 2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds [O] . Wardell, S M S V, Ferreira, M D, de Souza, M V N, 2006

机译：2,4-二氟苯甲醛苯甲酰and和2,4-二氯苯甲醛苯甲酰Z在120 K下具有Z'= 2的同构结构：由NH中心点中心点中心点O，CH中心点中心点中心点O和CH中心点中心组成的复合片点中心点pi（芳烃）氢键

Short S=O center dot center dot center dot C=O contacts associate diastereomers of 2,4(6)-di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-orthoformate in their inclusion complexes

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