Hollow Nanospheres and Flowers of CuS from Self-Assembled Cu(II) Coordination Polymer and Hydrogen-Bonded Complexes of N-(2-Hydroxybenzyl)-L-serine

Nagarathinam M; Saravanan K; Leong WL; Balaya P; Vittal JJ

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Hollow Nanospheres and Flowers of CuS from Self-Assembled Cu(II) Coordination Polymer and Hydrogen-Bonded Complexes of N-(2-Hydroxybenzyl)-L-serine

机译：自组装的Cu（II）配位聚合物和N-（2-羟基苄基）-L-丝氨酸的氢键配合物形成的CuS空心纳米球和花

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Utilization of a novel two-dimensional coordination polymer generated from a trinuclear building block [Cu-3(HSser)(3)(H2O)(2)]center dot 2H(2)O (1) as a precursor in the synthesis of copper sulfide serendipitously resulted in CuS nanospheres with hollow interiors. The formation of CuS nanocrystals with the three-dimensional hierarchical flower-like morphology from the hydrogen-bonded metal complex [Cu(H(2)Sser)(2)]center dot H2O (2) as a precursor may be understood from the spatial arrangement of the metal atom and the organic ligand in the crystal lattice plays a major role in determining the shape of the nanomaterials. Detailed investigation on the effect of experimental conditions and the packing patterns of the complexes in the crystal lattice reveals the formation mechanism of the morphologically different CuS. The electrochemical behavior of these nanosized CuS meso-assemblies as a cathode material for lithium ion batteries reveals that the reaction proceeds through an insertion and deinsertion mechanism and the CuS with a hollow interior is more efficient and has good cyclability compared to that with a flower-like morphology.

机译：利用三核结构单元[Cu-3（HSser）（3）（H2O）（2）]中心点2H（2）O（1）生成的新型二维配位聚合物作为铜的合成前体硫化物偶然产生了具有空心内部的CuS纳米球。从氢键金属络合物[Cu（H（2）Sser）（2）]中心点H2O（2）作为前体可以形成具有三维分层花状形态的CuS纳米晶体。金属原子和有机配体在晶格中的排列在确定纳米材料的形状中起主要作用。详细研究实验条件和配合物在晶格中的堆积模式的影响，揭示了形态不同的CuS的形成机理。这些纳米级CuS介观组装体作为锂离子电池正极材料的电化学行为表明，反应是通过插入和去插入机制进行的，与花形内腔相比，具有中空内部的CuS更有效且具有良好的可循环性。像形态

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来源
《Crystal growth & design》 |2009年第10期|共10页
作者
Nagarathinam M; Saravanan K; Leong WL; Balaya P; Vittal JJ;
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正文语种 eng
中图分类 549B0001;
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OPTICAL-LIMITING PROPERTIES; SCHIFF-BASE LIGANDS; COPPER SULFIDE; CATECHOLASE ACTIVITY; SULFUR BATTERY; DRUG-DELIVERY; SPHERES; LITHIUM; ROUTE; NANOSTRUCTURES;

机译：光学极限特性;席夫夫基配体;铜硫化物;儿茶酚酶活性;硫电池;药物输送;球;锂;路线;纳米结构;

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1. Hollow Nanospheres and Flowers of CuS from Self-Assembled Cu(II) Coordination Polymer and Hydrogen-Bonded Complexes of N-(2-Hydroxybenzyl)-L-serine [J] . Nagarathinam M, Saravanan K, Leong WL, Crystal growth & design . 2009,第10期

机译：自组装的Cu（II）配位聚合物和N-（2-羟基苄基）-L-丝氨酸的氢键配合物形成的CuS空心纳米球和花
2. From Self-Assembled Cu(II) Coordination Polymer to Shape-Controlled CuS Nanocrystals [J] . Nagarathinam M, Chen JL, Vittal JJ Crystal growth & design . 2009,第5期

机译：从自组装的Cu（II）配位聚合物到形状控制的CuS纳米晶体
3. One-dimensional coordination polymers: Cu(II) and Zn(II) complexes of N-(2-pyridylmethyl)-glycine and N-(2-pyridylmethyl)-L-alanine [J] . Wang XB, Ranford JD, Vittal JJ Journal of Molecular Structure . 2006,第1a3期

机译：一维配位聚合物：N-（2-吡啶基甲基）-甘氨酸和N-（2-吡啶基甲基）-L-丙氨酸的Cu（II）和Zn（II）配合物
4. Fabrication of Copper Chloride Hydroxide Nanoflowers from Au-Cu Hollow Nanospheres Using a Solution-phase Methodology [C] . Min-Dian Siao, Chen-Sheng Yeh IEEE Conference on Nanotechnology . 2005

机译：使用溶液 - 阶段方法从Au-Cu中空纳米球制备氯化铜氯化铜纳米辊
5. Catalytic Performance of a New 1D Cu(II) Coordination Polymer {Cu(NO3)(H2O)}(HTae)(44′-Bpy) for Knoevenagel Condensation [O] . Edurne S. Larrea, Roberto Fernández de Luis, María I. Arriortua 2016

机译：新型一维Cu（II）配位聚合物{Cu（NO3）（H2O）}（HTae）（44-Bpy）催化Knoevenagel缩合的性能
6. Isomerism in 1D Coordination Polymers of Cu(II) Complexes of N-(2-Hydroxybenzyl)-l-valine: Influence of Solvent and Coordination Sphere on the Conformation [O] . -1

机译：N-（2-羟基苄基）-L-缬氨酸Cu（II）配合物的1D配位聚合物中的异构性：溶剂和协调球体对构象的影响
7. Novel Square Pyramidal Copper(II) Complexes of the Stereospecific Linear NSNNTetradentate Ligand N-((2-Pyridyl)methyl)-2-((2-Aminoethyl)thio) Acetamide (pygeH). The Crystal Structures of (Cu(pyge)X) (X = Br, N3) [R] . Toscano, P. J., Fordon, K. J., Macherone, D., 1990

机译：新型方形金字塔形铜（II）配合物的立体特异性线性NsNN四齿配体N - （（2-吡啶基）甲基）-2 - （（2-氨基乙基）硫代）乙酰胺（pygeH）。（Cu（pyge）X）（X = Br，N3）的晶体结构

Hollow Nanospheres and Flowers of CuS from Self-Assembled Cu(II) Coordination Polymer and Hydrogen-Bonded Complexes of N-(2-Hydroxybenzyl)-L-serine

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