Construction of metal-organic frameworks with novel {Zn_8O _(13)} SBU or chiral channels through in situ ligand reaction

Hu T.; Bi W.; Hu X.; Zhao X.; Sun D.

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Construction of metal-organic frameworks with novel {Zn_8O _(13)} SBU or chiral channels through in situ ligand reaction

机译：通过原位配体反应构建具有新型{Zn_8O _（13）} SBU或手性通道的金属有机骨架

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By control of in situ ligand reaction, two zinc metal-organic frameworks (1, 2) have been isolated hydrothermally. Both complexes are 3D open frameworks. Complex 1, which is based on an unprecedented {Zn_8O_(13)} SBU constructed of 2H-imidazole-4,5-dicarboxylic acid (H_3IMDC), has the same topology as that of MOF-5. Complex 2 contains large homochiral channels based on the in situ generated 4,5-di(1H-tetrazol-5-yl)-2H-imidazole (H _3DTIM). Both H_3IMDC and H_3DTIM ligands are in situ generated from the same precursor, 2H-imidazole-4,5-dicarbonitrile.

机译：通过控制原位配体反应，水热分离了两个锌金属-有机骨架（1、2）。这两个复合体都是3D开放框架。络合物1基于2H-咪唑-4,5-二羧酸（H_3IMDC）构成的前所未有的{Zn_8O_（13）} SBU，其拓扑结构与MOF-5相同。配合物2包含基于原位生成的4,5-二（1H-四唑-5-基）-2H-咪唑（H _3DTIM）的大同手性通道。 H_3IMDC和H_3DTIM配体都是由相同的前体2H-咪唑-4,5-二碳腈原位生成的。

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《Crystal growth & design》 |2010年第8期|共3页
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Hu T.; Bi W.; Hu X.; Zhao X.; Sun D.;
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中图分类晶体学;
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1. Construction of metal-organic frameworks with novel {Zn_8O _(13)} SBU or chiral channels through in situ ligand reaction [J] . Hu T., Bi W., Hu X., Crystal growth & design . 2010,第8期

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3. Chiral Cadmium(II) Metal-Organic Framework from an Achiral Ligand by Spontaneous Resolution: An Efficient Heterogeneous Catalyst for the Strecker Reaction of Ketones [J] . Verma Ashish, Tomar Kapil, Bharadwaj Parietal K. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2017,第22期

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Construction of metal-organic frameworks with novel {Zn_8O _(13)} SBU or chiral channels through in situ ligand reaction

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