Alkyne-Functionalized Ruthenium Nanoparticles: Impact of Metal-Ligand Interfacial Bonding Interactions on the Selective Hydrogenation of Styrene

Zhang Fengqi; Fang Jingjing; Huang Lin; Sun Wenming; Lin Zhang; Shi Zhenqing; Kang Xiongwu; Chen Shaowei

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Alkyne-Functionalized Ruthenium Nanoparticles: Impact of Metal-Ligand Interfacial Bonding Interactions on the Selective Hydrogenation of Styrene

机译：炔烃官能化钌纳米粒子：金属 - 配体界面粘合相互作用对苯乙烯选择性氢化的影响

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In the present study, ruthenium nanoparticles functionalized with terminal and internal alkynes were prepared, and it was found that internal alkynes formed a eta(2) side-on configuration on the surface of ruthenium nano particles, in sharp contrast to the ruthenium-vinylidene interfacial bonds for terminal alkynes. For the nanoparticles capped with terminal alkyne, hydrogenation of both the vinyl moiety and phenyl ring occurred, whereas selective hydrogenation of the vinyl moiety was observed with internal alkyne-functionalized nanoparticles. This work highlights the importance of the metal-organic interface in the rational design and engineering of the nanoparticle catalyst for organic synthesis.

机译：在本研究中，制备用末端和内部炔烃官能化的钌纳米颗粒，发现内酯在钌纳米颗粒表面上形成ETA（2）侧构型，与钌 - 亚乙烯基界面鲜明对比艾基末端的债券。对于用末端炔烃盖上纳米颗粒的纳米颗粒，发生乙烯基部分和苯基环的氢化，而用内酯官能化纳米颗粒观察乙烯基部分的选择性氢化。这项工作突出了金属有机界面在纳米粒子催化剂的合理设计和工程中的有机合成的重要性。

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来源
《ACS catalysis》 |2019年第1期|共7页
作者
Zhang Fengqi; Fang Jingjing; Huang Lin; Sun Wenming; Lin Zhang; Shi Zhenqing; Kang Xiongwu; Chen Shaowei;
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作者单位

South China Univ Technol Guangzhou Higher Educ Mega Ctr Guangzhou Key Lab Surface Chem Energy Mat New Energy Res Inst Sch Environm &

Energy Guangzhou 510006 Guangdong Peoples R China;

South China Univ Technol Guangzhou Higher Educ Mega Ctr Guangzhou Key Lab Surface Chem Energy Mat New Energy Res Inst Sch Environm &

Energy Guangzhou 510006 Guangdong Peoples R China;

South China Univ Technol Guangzhou Higher Educ Mega Ctr Guangzhou Key Lab Surface Chem Energy Mat New Energy Res Inst Sch Environm &

Energy Guangzhou 510006 Guangdong Peoples R China;

China Bldg Mat Acad State Key Lab Green Bldg Mat Beijing 100041 Peoples R China;

South China Univ Technol Sch Environm &

Energy Guangdong Engn &

Technol Res Ctr Environm Nanomat Guangzhou 510006 Guangdong Peoples R China;

South China Univ Technol Sch Environm &

Energy Guangdong Engn &

Technol Res Ctr Environm Nanomat Guangzhou 510006 Guangdong Peoples R China;

South China Univ Technol Guangzhou Higher Educ Mega Ctr Guangzhou Key Lab Surface Chem Energy Mat New Energy Res Inst Sch Environm &

Energy Guangzhou 510006 Guangdong Peoples R China;

South China Univ Technol Guangzhou Higher Educ Mega Ctr Guangzhou Key Lab Surface Chem Energy Mat New Energy Res Inst Sch Environm &

Energy Guangzhou 510006 Guangdong Peoples R China;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
ruthenium nanoparticles; internal alkyne; eta(2) side-on configuration; sigma-pi covalent; interfacial charge transfer; styrene hydrogenation;

机译：钌纳米粒子;内部炔;ETA（2）侧面配置;Sigma-PI共价;界面电荷转移;苯乙烯氢化;

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专利

1. Alkyne-Functionalized Ruthenium Nanoparticles: Impact of Metal-Ligand Interfacial Bonding Interactions on the Selective Hydrogenation of Styrene [J] . Zhang Fengqi, Fang Jingjing, Huang Lin, ACS catalysis . 2019,第1期

机译：炔烃官能化钌纳米粒子：金属 - 配体界面粘合相互作用对苯乙烯选择性氢化的影响
2. Enhanced catalytic oxidation performance of K+-modified Ti-MWW through selective breaking of interfacial hydrogen-bonding interactions of H2O2 [J] . Yu Yunkai, Tang Zhimou, Liu Wei, Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2019,第期

机译：通过选择性破裂H2O2的界面氢键相互作用，增强K +型晶化Ti-MWW的催化氧化性能
3. Assembly of Metal Nanoparticles on Electrospun Nylon 6 Nanofibers by Control of Interfacial Hydrogen-Bonding Interactions [J] . Hong Dong, Dong Wang, Gang Sun Chemistry of Materials: A Publication of the American Chemistry Society . 2008,第21期

机译：通过控制界面氢键相互作用在静电纺丝尼龙6纳米纤维上组装金属纳米颗粒
4. Ruthenium Complex-catalyzed Highly Selective Dimerization of Styrenes and Linear Codimerization of Styrenes with Ethylene [C] . Teruyuki Kondo, Daisuke Takagi, Hiroshi Tsujita Symposium on Organometallic Chemistry . 2006

机译：钌复合催化苯乙烯和乙烯线性分析的高度选择性二聚化
5. Iridium Catalyzed C-H Borylation: Improved Selectivity by Electrostatic and Hydrogen-Bond Interactions and Applications to Deuteration and Ligand Synthesis. [D] . Gore, Kristin Anne. 2017

机译：铱催化的C-H硼化：通过静电和氢键相互作用提高的选择性以及在氘代和配体合成中的应用。
6. Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation [O] . Mr. Hongde Xiao, Mr. Gang Wang, Prof. Michael J. Krische -1

机译：钌催化的C-C键形成转移加氢使苯乙烯与伯醇或醛进行区域选择性氢羟烷基化
7. Anion-Selective Interaction and Colorimeter by an Optical Metalloreceptor Based on Ruthenium(II) 2, 2-Biimidazole: Hydrogen Bonding and Proton Transfer [O] . -1

机译：基于钌（II）2,2-双咪唑的光学金属聚体的阴离子选择性相互作用和色度计：氢键和质子转移

Alkyne-Functionalized Ruthenium Nanoparticles: Impact of Metal-Ligand Interfacial Bonding Interactions on the Selective Hydrogenation of Styrene

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