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首页> 外文期刊>ACS Macro Letters >100th Anniversary of Macromolecular Science Viewpoint: Engineering Supramolecular Materials for Responsive Applications-Design and Functionality
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100th Anniversary of Macromolecular Science Viewpoint: Engineering Supramolecular Materials for Responsive Applications-Design and Functionality

机译:大分子科学观点100周年:响应应用的工程超分子材料 - 设计和功能

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摘要

Supramolecular polymers allow access to dynamic materials, where noncovalent interactions can be used to offer both enhanced material toughness and stimuli-responsiveness. The versatility of self-assembly has enabled these supramolecular motifs to be incorporated into a wide array of glassy and elastomeric materials; moreover, the interaction of these noncovalent motifs with their environment has shown to be a convenient platform for controlling material properties. In this Viewpoint, supramolecular polymers are examined through their self-assembly chemistries, approaches that can be used to control their self-assembly (e.g., covalent cross-links, nanofillers, etc.), and how the strategic application of supramolecular polymers can be used as a platform for designing the next generation of smart materials. This Viewpoint provides an overview of the aspects that have garnered interest in supramolecular polymer chemistry, while also highlighting challenges faced and innovations developed by researchers in the field.
机译:超分子聚合物允许进入动态材料,其中非共价相互作用可用于提供增强的材料韧性和刺激反应性。自组装的多功能性使得这些超分子基序将其掺入宽玻璃和弹性体材料中;此外,这些非共价基序与其环境的相互作用已经显示为控制材料特性的方便平台。在该观点中,通过其自组装化学检测超分子聚合物,可以用于控制其自组装的方法(例如,共价交联,纳米填料等),以及如何浸焦聚合物的战略应用如何用作设计下一代智能材料的平台。这一观点概述了对超分子聚合物化学获得兴趣的方面的概述,同时还突出了该领域研究人员所产生的面临的挑战和创新。

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