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Species‐Dependent Chromium Isotope Fractionation Across the Eastern Tropical North Pacific Oxygen Minimum Zone

机译:依赖于东部热带北太平洋氧气最小区域的物种依赖性铬同位素分级

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Abstract > The stable chromium (Cr) isotope system is an emerging paleoredox proxy. Interpretation of sedimentary and seawater δ 53 Cr ( 53 Cr/ 52 Cr relative to SRM 979) hinges on our understanding of the isotopic fractionations during Cr sequestration from seawater to sediments. Seawater δ 53 Cr values reported thus far are for total dissolved Cr. This study reports the δ 53 Cr of both dissolved Cr (III) and dissolved Cr (VI) across the oxygen minimum zone in the eastern tropical North Pacific off Manzanillo, Mexico. Dissolved Cr (III) accounts for 48% to 54% total dissolved Cr in this region. There are no correlations between O <sub>2</sub> and Cr concentrations, or O <sub>2</sub> concentrations and δ 53 Cr throughout the water column. The δ 53 Cr of Cr (III) is lower than that of Cr (VI) by a relatively constant offset (0.42 ± 0.15‰, 1 σ , n = 5) and is also uncorrelated with dissolved O <sub>2</sub> concentration. These observations provide part of the foundation for using δ 53 Cr of the authigenic Cr in organic‐rich shales to reconstruct seawater δ 53 Cr. A survey of growing literature Cr concentration and δ 53 Cr data suggests that the Cr isotope fractionation factor in the global ocean is likely more complex than previously thought. More future species‐dependent Cr isotope studies could shed new light on the biogeochemical processes controlling the oceanic Cr isotope fractionation. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> > 稳定的铬(Cr)同位素系统是一个新兴的古罗铁赛代理。解释沉积和海水δ 53 </ sup> Cr( 53 </ sup> CR / 52 </ sup> CR相对于SRM 979)关于我们在从海水中沉积到沉积物期间对同位素分馏的理解。海水δ. 53 </ sup> 迄今为止报告的CR值是总溶解的CR。本研究报告了δ 53 </ sup> 溶解的Cr(iii)的Cr溶解的Cr(iii)和溶解的Cr(vi)在东方热带北太平洋的墨西哥曼萨尼诺曼萨尼洛省的东部热带北太平洋中的氧气最小区域。溶解的CR(iii)占该地区的48%至54%溶解CR。 o之间没有相关性 <sub> 2 </ sub> 和Cr浓度,或o <sub> 2 </ sub> 浓度和δ 53 </ sup> 在整个水柱中cr。 δ 53 </ sup> Cr(iii)的Cr通过相对恒定的偏移低于Cr(vi)的Cr(0.42±0.15‰,1 σ</ i> 那 n </ i> = 5)并且也与溶解o不相关 <sub> 2 </ sub> 专注。这些观察结果为使用δ提供部分基础 53 </ sup> 关于有机富有的Shales中的Authigenic Cr的CR重建海水δ 53 </ sup> CR。越来越多的文学CR浓度和δ的调查 53 </ sup> CR数据表明全球海洋中的CR同位素分级因子可能比以前认为更复杂。更新的物种依赖性Cr同位素研究可以在控制海洋Cr同位素分级的生物地球化学过程中阐明新的光。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-23285/'>《Geochemistry, geophysics, geosystems》</a> <b style="margin: 0 2px;">|</b><span>2019年第5期</span><b style="margin: 0 2px;">|</b><span>共16页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xiangli&option=202" target="_blank" rel="nofollow">Wang Xiangli;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Glass Jennifer B.&option=202" target="_blank" rel="nofollow">Glass Jennifer B.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Reinhard Chris T.&option=202" target="_blank" rel="nofollow">Reinhard Chris T.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Planavsky Noah J.&option=202" target="_blank" rel="nofollow">Planavsky Noah J.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Marine SciencesUniversity of South AlabamaMobile AL USA;</p> <p>Georgia Institute of TechnologyAtlanta GA USA;</p> <p>Georgia Institute of TechnologyAtlanta GA USA;</p> <p>Yale UniversityNew Haven CT USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/163.html" title="地球物理学">地球物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=chromium isotopes&option=203" rel="nofollow">chromium isotopes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=chromium speciation&option=203" rel="nofollow">chromium speciation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxygen minimum zone&option=203" rel="nofollow">oxygen minimum zone;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=paleoredox proxy&option=203" rel="nofollow">paleoredox proxy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=eastern tropical North Pacific&option=203" rel="nofollow">eastern tropical North Pacific;</a> </p> <div class="translation"> 机译:铬同位素;铬形状;氧气最小区域;古罗统索代理;东部热带北太平洋; 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