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EARLY STAGES OF CRYSTALLIZATION OF LANTHANUM-BOROGERMANATE GLASS BY A FEMTOSECOND LASER BEAM

机译:飞秒激光束通过镧 - 硼烷玻璃结晶的早期阶段

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摘要

Regions in the bulk of lanthanum borogermanate glass modified by a femtosecond laser beam were studied by means of optical microscopy and confocal Raman scattering (RS) spectroscopy. The obtained data show that, at the stages preceding the formation of an LaBGeO5 microcrystal, upon irradiation by a femtosecond beam in a certain interval of laser pulse energy germanium nanocrystals precipitate in the zone of local heating. The correlation between the conditions of laser irradiation leading to the appearance of germanium nanocrystals and the conditions ensuring with high probability the crystallization of phases of the low-temperature modification of lanthanum borate and stillwellite-like lanthanum borogermanate suggest that germanium nanocrystals can serve as nuclei for heterogeneous crystallization of LaBO3 and LaBGeO3.
机译:通过光学显微镜和共聚焦拉曼散射(RS)光谱法研究由飞秒激光束改性的大部分镧硼合格兰玻璃的区域。 所获得的数据表明,在局部加热区中的激光脉冲能量锗纳米晶沉淀的特定间隔之前,在形成Labgeo5微晶的阶段,在局部加热区域中的一定间隔照射。 激光照射条件之间的相关性导致锗纳米晶体的外观和高概率的条件,镧硼酸镧和Stillwerate镧硼烷的低温改性阶段的结晶表明锗纳米晶体可以用作核 Labo3和Labgeo3的异质结晶。

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