首页> 外文期刊>Crystal Research and Technology: Journal of Experimental and Industrial Crystallography >Flux growth of La-doped lead zirconate stannate titanate antiferroelectric crystals
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Flux growth of La-doped lead zirconate stannate titanate antiferroelectric crystals

机译:镧掺杂锆酸锡钛酸钛反铁电晶体的通量生长

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摘要

Relaxor antiferroelectric single crystals lead lanthanum zirconate stannate titanate (PLZST) with the composition around the morphotropic phase boundary (MPB) have been grown by flux method using 50 wt% PbO-PbF2-B2O3, as a flux. The obtained crystals are light yellow in color. The XRD patterns revealed that the habitual faces of the obtained crystal are (001). The crystal morphology was studied and related to a layer growth mechanism controlled by two-dimensional growth. The chemical composition of as-grown crystal was analyzed by inductively coupled plasma atomic emission spectrometry (ICP), indicating a slight decrease of the amount of Ti compared to the starting materials. The result was verified by the XRD patterns with the phase transformation from the co-existence of tetragonal and rhombohedra phases to the single tetragonal phase. (C) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
机译:使用50wt%的PbO-PbF2-B2O3作为助熔剂,通过助熔剂法生长了弛豫反铁电单晶锆酸镧锡酸钛酸铅(PLZST),在变质相界(MPB)周围。所得晶体为浅黄色。 XRD图谱表明,所得晶体的惯性面为(001)。研究了晶体形态并与二维生长控制的层生长机理有关。通过电感耦合等离子体原子发射光谱法(ICP)分析了晶体的化学成分,表明与起始材料相比,Ti的含量略有下降。通过XRD图案验证了结果,该图具有从四方相和菱形相的共存到单个四方相的相变。 (C)2008 WILEY-VCH Verlag GmbH&Co.KGaA,Weinheim

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