Crystal and molecular structures of trans-2-(4 '-dimethylaminobenzylideneacetyl)-5,5-dimethylcyclohexane-1,3-dione

Bondarev SL; Lyakhov AS; Pyrko AN; Govorova AA; Kalosha II; Knyukshto VN

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Crystal and molecular structures of trans-2-(4 '-dimethylaminobenzylideneacetyl)-5,5-dimethylcyclohexane-1,3-dione

机译：反式-2-（4'-二甲基氨基亚苄基乙酰基）-5,5-二甲基环己烷-1,3-二酮的晶体和分子结构

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The crystal and molecular structures of a cyclic beta-triketone, namely, trans-2-(4'-dimethylaminobenzylideneacetyl)-5,5-dimethylcyclohexane-1,3-dione (1), are determined using X-ray diffraction analysis. It is established that the compound in the crystalline state exists in a diketo-enol form stabilized by intramolecular hydrogen bonds. The specific features of the structure and the physicochemical and fluorescence properties of the compound are discussed. (c) 2005 Pleiades Publishing, Inc.

机译：使用X射线衍射分析确定环状β-三酮，即反式-2-（4'-二甲基氨基亚苄基乙酰基）-5,5-二甲基环己烷-1,3-二酮（1）的晶体和分子结构。已经确定结晶状态的化合物以通过分子内氢键稳定的二酮-烯醇形式存在。讨论了该化合物的结构特征，理化性质和荧光性质。（c）2005年Pleiades Publishing，Inc.

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《Crystallography reports》 |2005年第3期|共6页
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Bondarev SL; Lyakhov AS; Pyrko AN; Govorova AA; Kalosha II; Knyukshto VN;
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Crystal and molecular structures of trans-2-(4 '-dimethylaminobenzylideneacetyl)-5,5-dimethylcyclohexane-1,3-dione

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