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Variations in the structure of aromatic solvents under the influence of dissolved fullerene C-70

机译:溶解的富勒烯C-70影响下芳族溶剂结构的变化

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摘要

Dilute solutions of the C-70 fullerene (at concentrations from 0.0001-0.0005% to a few hundredths of a percent) in benzene, toluene, and p-xylene are investigated using small-angle and wide-angle X-ray diffraction. It is revealed that an increase in the C-70 fullerene concentration leads to a nonmonotonic shift of the small-angle X-ray diffraction patterns along the intensity axis: the intensity first decreases, reaches a minimum, and then increases. The wide-angle X-ray diffraction patterns of all the solutions under investigation exhibit two halos: as the fullerene concentration in the solution increases, the intensity of the first halo increases, whereas the intensity of the second halo decreases. The variations observed in the X-ray diffraction patterns of the fullerene solutions are interpreted in terms of structuring of the solvents, i.e., the formation of a specific order on the molecular and supramolecular levels. The X-ray diffraction data are in good agreement with the nonmonotonic concentration dependences of the density of the fullerene solutions in aromatic solvents. A structural interpretation of the initial decrease in the density of the fullerene solutions is proposed.
机译:使用小角和广角X射线衍射研究了C-70富勒烯在苯,甲苯和对二甲苯中的稀释溶液(浓度为0.0001-0.0005%至百分之几的百分数)。揭示了C-70富勒烯浓度的增加导致小角X射线衍射图沿强度轴的非单调移动:强度首先降低,达到最小值,然后升高。所有所研究溶液的广角X射线衍射图都有两个晕圈:随着溶液中富勒烯浓度的增加,第一个晕圈的强度增加,而第二个晕圈的强度减小。富勒烯溶液在X射线衍射图中观察到的变化是根据溶剂的结构,即在分子和超分子水平上形成特定顺序而解释的。 X射线衍射数据与芳族溶剂中富勒烯溶液的密度的非单调浓度依赖性很好。提出了富勒烯溶液密度的初始降低的结构解释。

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