Synthesis and structure of methyl 8-allyl-6-bromo-2-methyl-1,2,3,4- tetrahydroquinoline-4-carboxylate

Zhuravleva Yu.A.; Zimichev A.V.; Zemtsova M.N.; Rybakov V.B.; Klimochkin Y.N.

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Synthesis and structure of methyl 8-allyl-6-bromo-2-methyl-1,2,3,4- tetrahydroquinoline-4-carboxylate

机译：8-烯丙基-6-溴-2-甲基-2-1,2,3,4-四氢喹啉-4-羧酸甲酯的合成与结构

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The compound C_(15)H_(18)NO_2Br was synthesized and characterized by X-ray diffraction. The crystals belong to the monoclinic system, sp. gr. P2_1, a = 8.913(2) ?, b = 23.637(6) ?, c = 13.892(3) ?, β = 90.31(2)°, Z = 8, V = 2926.8(12) ?~3, ρ_(calc) = 1.472 g/cm~3. The bond lengths and bond angles in two molecules are equal within an experimental error and are typical of this class of compounds. The conformational differences of the saturated heterocyclic and methoxycarbonyl fragments of the molecules result in the presence of two crystallographically independent molecules in the crystal structure.

机译：合成了化合物C_（15）H_（18）NO_2Br，并通过X射线衍射对其进行了表征。晶体属于单斜晶系，sp。 gr。 P2_1 / n，a = 8.913（2）α，b = 23.637（6）α，c = 13.892（3）α，β= 90.31（2）°，Z = 8，V = 2926.8（12）α〜3， ρ_（计算）＝ 1.472g / cm〜3。在实验误差范围内，两个分子的键长和键角相等，是此类化合物的典型特征。分子的饱和杂环和甲氧羰基片段的构象差异导致晶体结构中存在两个晶体学独立的分子。

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《Crystallography reports》 |2010年第5期|共4页
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Zhuravleva Yu.A.; Zimichev A.V.; Zemtsova M.N.; Rybakov V.B.; Klimochkin Y.N.;
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Synthesis and structure of methyl 8-allyl-6-bromo-2-methyl-1,2,3,4- tetrahydroquinoline-4-carboxylate

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