Fe-2.5[BP2O7(OH)(2)][PO3(OH)][PO3(O0.5OH0.5)] center dot H2O, a new phosphate-borophosphate with a microporous structure

Belokoneva E. L.; Dimitrova O. V.

首页> 外文期刊>Crystallography reports >Fe-2.5[BP2O7(OH)(2)][PO3(OH)][PO3(O0.5OH0.5)] center dot H2O, a new phosphate-borophosphate with a microporous structure

【24h】

Fe-2.5[BP2O7(OH)(2)][PO3(OH)][PO3(O0.5OH0.5)] center dot H2O, a new phosphate-borophosphate with a microporous structure

机译：Fe-2.5 [BP2O7（OH）（2）] [PO3（OH）] [PO3（O0.5OH0.5）]中心点H2O，一种具有微孔结构的新型磷酸盐-硼磷酸盐

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new phosphate-borophosphate Fe (2.5) (3+) [BP2O7(OH)(2)][PO3(OH)][PO3(O0.5OH0.5)] center dot H2O, space group P12(1), is obtained under hydrothermal conditions. Blocks {Fe3+(PO4)(6)}(15-) consisting of vertex-sharing (Fe1,Fe2)O-6 octahedra and six PO4 tetrahedra are distinguished in the structure of the new phase, which was determined without preliminary knowledge of the chemical formula. Such blocks are known for many phosphates (borophosphates), germanates, gallates, and silicates. Blocks form layers connected by BO4 tetrahedra into a framework with large pores reaching similar to 9.5 angstrom, which are occupied by water molecules. The out-of-layer octahedral position of the Fe3 atom is split and occupied statistically. The anion radical is characterized as a phosphate-borophosphate: it consists of two isolated PO4 tetrahedra and a borophosphate soro group [BP2O7(OH)(2)] first found in NaIn[BP2O8(OH)]. A layer of octahedra is characterized by higher local symmetry corresponding to the orthorhombic group Pm2(1) n.

机译：一种新的磷酸盐-硼磷酸盐Fe（2.5）（3+）[BP2O7（OH）（2）] [PO3（OH）] [PO3（O0.5OH0.5）]中心点H2O，空间组P12（1）/ n是在水热条件下获得的。由顶点共享（Fe1，Fe2）O-6八面体和六个PO4四面体组成的{Fe3 +（PO4）（6）}（15-）嵌段在新相的结构中得到了区分，这是在没有初步了解的情况下确定的化学式。对于许多磷酸盐（硼磷酸盐），锗酸盐，没食子酸盐和硅酸盐而言，此类嵌段是已知的。块形成由BO4四面体连接的层，形成一个骨架，该骨架的大孔接近9.5埃，被水分子占据。 Fe3原子的层外八面体位置被拆分并被统计占据。阴离子基团的特征是磷酸-硼磷酸根：它由两个分离的PO4四面体和一个硼酸根单独基团[BP2O7（OH）（2）]首次存在于NaIn [BP2O8（OH）]中。八面体层的特征在于与斜方基团Pm2（1）n对应的较高局部对称性。

著录项

来源
《Crystallography reports》 |2015年第3期|共6页
作者
Belokoneva E. L.; Dimitrova O. V.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. Fe-2.5[BP2O7(OH)(2)][PO3(OH)][PO3(O0.5OH0.5)] center dot H2O, a new phosphate-borophosphate with a microporous structure [J] . Belokoneva E. L., Dimitrova O. V. Crystallography reports . 2015,第3期

机译：Fe-2.5 [BP2O7（OH）（2）] [PO3（OH）] [PO3（O0.5OH0.5）]中心点H2O，一种具有微孔结构的新型磷酸盐-硼磷酸盐
2. Hybrid open frameworks. Hydrothermal synthesis, structure determinations, and magnetic behavior of ((VO)-O-IV)(2)(H2O){O3P-(CH2)(3)-PO3} center dot 2H(2)O: A new vanado-alkyldiphosphonate closely related to VO(HPO4) center dot 0.5H(2)O [J] . Riou D., Provost J., Ferey G., International Journal of Quantum Chemistry . 2000,第1期

机译：混合开放框架。（（VO）-O-IV）（2）（H2O）{O3P-（CH2）（3）-PO3}中心点2H（2）O的水热合成，结构确定和磁性行为：一种新的钒烷基二膦酸酯与VO（HPO4）中心点0.5H（2）O密切相关
3. Hybrid open frameworks. 8. Hydrothermal synthesis, crystal structure, and thermal behavior of the first three-dimensional titanium(IV) diphosphonate with an open structure: Ti3O2(H2O)(2)(O3P-(CH2)-PO3)(2)center dot(H2O)(2), or MIL-22 [J] . Serre C., Ferey G. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第23期

机译：混合开放框架。 8.具有开孔结构的第一个三维三维二膦酸钛（IV）的水热合成，晶体结构和热行为：Ti3O2（H2O）（2）（O3P-（CH2）-PO3）（2）中心点（H2O））（2）或MIL-22
4. Hydrothermal Synthesis and Characterization of a New Three -dimensional FrameworkVanadium Phosphate phosphite Material: V(H2O)6V2 PO3(OH)12HPO32· 2HIm· H2Im [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：新型三维骨架磷酸亚磷酸钒材料的水热合成与表征：V（H2O） 6V2 PO3（OH） 12 HPO3 2·2HIm·H2Im
5. Synthesis and characterization of mixed-valence manganese fluorophosphate and analogues with clathrate-like structures: MnIII6F12(PO3(OH))8Na8(Kx(H3O)4−x(H2O)2)MIV(OH)6 (MIV = Mn, Ti, Ge) [O] . Wei-Jian Ren, Jing-Quan Wang, Ya-Xi Huang, 2015

机译：混合价氟磷酸氟磷酸盐的合成与表征用克拉酸盐状结构：MnIII6F12（PO 3（OH））8 Na8（KN（H3O）4-x（H2O）2）MiV（OH）6（MIV = Mn ，ti，ge）
6. Formation and Structure of Al(PO3)3 System Glasses [R] . Gan, F., Jiang, Y., Jiang, F. 1982

机译：al（pO3）3系统玻璃的形成与结构

Fe-2.5[BP2O7(OH)(2)][PO3(OH)][PO3(O0.5OH0.5)] center dot H2O, a new phosphate-borophosphate with a microporous structure

摘要

著录项

相似文献

相关主题

期刊订阅