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The mycoestrogen zearalenone in Portuguese flowing waters and its potential environmental impact

机译:葡萄牙语流动水域中的硫酸硫代酸盐酮酮及其潜在的环境影响

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摘要

This study provides the first environmental risk assessment (ERA) for zearalenone (ZEN), the only known mycoestrogen, based on a broad-scale investigation on its occurrence in rivers and creeks from Portugal. Water sample filtration and inmnmoafflnitycolumns (IAC) clean-up followed by liquid chromatograph with tandem mass spectrometry (LC/MS") provided an analytical method with good analytical performance. ZEN levels were determined for seven Portuguese rivers and one creek, during two different seasons, in a total of 38 samples collected upstream wastewater treatment plants (WWTPs). Overall, 23.7% were contaminated with ZEN at levels ranging between 5.6 and 82.6 ng/L. The highest concentration was observed during spring, although no statisticallysignificant differences were observed between spring and autumn sampling campaigns. The potential ecotoxicological risk from ZEN to different trophic levels of aquatic organisms was evaluated by means of risk quotients (RQs) calculation. Although all theRQs obtained were lower than 1, our results confirm that ZEN is a relatively frequent contaminant in flowing waters in Portugal and might contribute to the overall estrogenic activity in the environment.
机译:本研究为Zearalenone(ZEN)的第一个环境风险评估(ERA)是基于葡萄牙河流和小溪事件的广泛调查。水样过滤和INMMoafflnityColumns(IAC)清理,然后进行串联质谱(LC / MS“)的液相色谱仪提供了一种具有良好分析性能的分析方法。在两个不同的季节,ZEN水平测定了七个葡萄牙河和一条小溪,总共38个样品收集的上游废水处理厂(WWTPS)。总体而言,23.7%的含量在5.6%和82.6 ng / L之间的水平污染。春季期间观察到最高的浓度,尽管之间未观察到统计学上无关的差异春季和秋季采样运动。通过风险报价(RQS)计算评估来自禅宗到不同营养水平水生生物水平的潜在生态毒理风险。尽管所获得的所有THER都低于1,但我们的结果证实ZEN是相对频繁的污染物在葡萄牙的流水中,可能有助于环境中的整体雌激素活动m。

著录项

  • 来源
    《Mycotoxin Research》 |2018年第1期|共7页
  • 作者单位

    LAQV REQUIMTE Laboratory of Bromatology and Pharmacognosy Faculty of Pharmacy University of Coimbra Polo HI Azinhaga de St" Comba 3000-548 Coimbra Portugal;

    LAQV REQUIMTE Laboratory of Bromatology and Pharmacognosy Faculty of Pharmacy University of Coimbra Polo HI Azinhaga de St" Comba 3000-548 Coimbra Portugal;

    LAQV REQUIMTE Laboratory of Bromatology and Pharmacognosy Faculty of Pharmacy University of Coimbra Polo HI Azinhaga de St" Comba 3000-548 Coimbra Portugal;

    LAQV REQUIMTE Laboratory of Bromatology and Pharmacognosy Faculty of Pharmacy University of Coimbra Polo HI Azinhaga de St" Comba 3000-548 Coimbra Portugal;

    LAQV REQUIMTE Laboratory of Bromatology and Pharmacognosy Faculty of Pharmacy University of Coimbra Polo HI Azinhaga de St" Comba 3000-548 Coimbra Portugal;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 Q939.5;
  • 关键词

    Zearalenone; Flowing surface waters; Occurrence; Risk assessment;

    机译:Zearalenone;流动的表面水;发生;风险评估;

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