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Fabrication and magnetorheology of bidisperse magnetic microspheres coated with gelatin and multi-walled carbon nanotubes

机译:涂有明胶和多壁碳纳米管的双孔磁性微球的制造和磁流变

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摘要

To improve the magnetorheological (MR) properties and dispersion stability of the carbonyl iron (CI) particles, bidisperse magnetorheological (BMR) fluids consisting of magnetic micron-sized CI and nanoparticles dual-coated with gelatin and multi-walled carbon nanotubes (MWCNTs) were synthesized for the first time. Gelatin was used as a grafting agent to improve the stability of bidisperse magnetic particles and restrict the oxidation of nanoparticles (Fe3O4). And a dense network composed of MWCNTs on the surface of gelatin-coated bidisperse particles was fabricated based on the self-assembly of MWCNTs to produce considerably rough surfaces. The influence of functional dual-coated layer on rheological performance such as shear stress and yield stress behavior was investigated by a rotational rheometer upon various magnetic field applications. Additionally, the dispersion stability was measured through sedimentation tests. The results showed that CI-Fe3O4-Gelatin-MWCNTs (CI-Fe3O4-G-NT) magnetic microspheres possessed enhanced MR properties compared with those from CI-Fe3O4-Gelatin (CI-Fe3O4-G) microspheres, while the dispersion stability of CI-Fe3O4-G-NT microspheres was still maintained.
机译:为了改善羰基铁(CI)颗粒的磁流变(MR)性能和分散稳定性,由磁性微米尺寸Ci和纳米颗粒组成的磁性微集液(BMR)流体与明胶和多壁碳纳米管(MWCNT)组成的磁性微米尺寸和纳米颗粒组成第一次合成。明胶用作接枝剂以改善偏磁颗粒的稳定性,并限制纳米颗粒的氧化(Fe3O4)。并且基于MWCNT的自组装制造了由明胶涂覆的BID分散颗粒表面上的MWCNT构成的致密网络,以产生大大粗糙表面。在各种磁场应用上,通过旋转流变仪研究了功能双涂层对流变性能的影响,例如剪切应力和屈服应力行为。另外,通过沉降试验测量分散稳定性。结果表明,与C 1 -FE3O4-明胶(C 1 -FE3O4-G)微球相比,CI-Fe3O4-明胶-MWCNT(C 1 -FE3O4-G-NT)磁性微球具有增强的MR性能,而CI的分散稳定性-Fe3O4-G-NT微球仍然保持。

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