New Comb-Shaped Triblock Copolymers Containing a Liquid-Crystalline Block and Polyvinylpyridine Amorphous Blocks: Synthesis and Properties

Bugakov M. A.; Boiko N. I.; Chernikova E. V.; Abramchuk S. S.; Shibaev V. P.

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New Comb-Shaped Triblock Copolymers Containing a Liquid-Crystalline Block and Polyvinylpyridine Amorphous Blocks: Synthesis and Properties

机译：含有液晶嵌段和聚乙烯吡啶非晶块的新型梳形三嵌段共聚物：合成和性能

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New liquid-crystalline symmetric triblock copolymers ABA, in which central LC block B is poly(p-(6-acryloyloxycaproyloxyphenyl)-p-methoxybenzoate and blocks A are amorphous blocks of polyvinylpyridine, whose units are able to form various types of noncovalent chemical bonds, are synthesized. The phase behavior of the triblock copolymers is studied, and the type of their microphase-separated structure is ascertained. It is shown that the composition of the triblock copolymers affects the morphology of their thin films.

机译：新的液晶对称三嵌段共聚物ABA，其中中心LC嵌段B是聚（P-（6-丙烯酰氧基丙酰氧基苯甲酰基）-P-甲氧基苯甲酸酯和嵌段A是聚乙烯吡啶的无定形块，其单位能够形成各种类型的非共价化学键，是合成的。研究了三嵌段共聚物的相行为，并确定其微相分离结构的类型。显示三嵌段共聚物的组成影响其薄膜的形态。

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《Polymer science, Series C》 |2018年第1期|共11页
作者
Bugakov M. A.; Boiko N. I.; Chernikova E. V.; Abramchuk S. S.; Shibaev V. P.;
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Lomonosov Moscow State Univ Fac Chem Moscow 119991 Russia;

Lomonosov Moscow State Univ Fac Chem Moscow 119991 Russia;

Lomonosov Moscow State Univ Fac Chem Moscow 119991 Russia;

Lomonosov Moscow State Univ Fac Chem Moscow 119991 Russia;

Lomonosov Moscow State Univ Fac Chem Moscow 119991 Russia;

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中图分类有机化学;
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1. New Comb-Shaped Triblock Copolymers Containing a Liquid-Crystalline Block and Polyvinylpyridine Amorphous Blocks: Synthesis and Properties [J] . Bugakov M. A., Boiko N. I., Chernikova E. V., Polymer science, Series C . 2018,第1期

机译：含有液晶嵌段和聚乙烯吡啶非晶块的新型梳形三嵌段共聚物：合成和性能
2. Synthesis and properties of liquid-crystalline triblock copolymers by ATRP,having electron-transporting thiadiazole unit [J] . Shinji Nakashima, Moriyuki Sato, Isao Yamaguchi Polymer international . 2008,第1期

机译：含电子传输噻二唑单元的ATRP液晶三嵌段共聚物的合成与性能
3. CHIRAL ASSEMBLY IN AMORPHOUS ABC TRIBLOCK COPOLYMERS - FORMATION OF A HELICAL MORPHOLOGY IN POLYSTYRENE-BLOCK-POLYBUTADIENE-BLOCK-POLY(METHYL METHACRYLATE) BLOCK COPOLYMERS [J] . Krappe U., Voigtmartin I., Stadler R. Macromolecules . 1995,第13期

机译：非晶ABC三嵌段共聚物中的手性组装-聚苯乙烯-嵌段-聚丁二烯-嵌段-聚（甲基丙烯酸甲酯）嵌段共聚物的螺旋形态形成
4. Synthesis of Well-Defined Poly(ethylene-dimethylsiloxane-ethyelene) Triblock Copolymers by Diazene-Based Hydrogenation of Polybutadiene Blocks and their Bulk Self-Assembly Properties [C] . Nikos Petzetakis, Nitash Balsara National American Chemical Society Meeting . 2014

机译：用聚丁二烯块的重氮氢化氢化晶型聚（乙烯 - 二甲基硅氧烷 - 乙烯）三嵌段共聚物的合成及其散装自组装性能
5. Biodegradable triblock copolymer microspheres for drug delivery based on thermosensitive property of triblock copolymer. [D] . Kwon, Young Min. 2003

机译：基于三嵌段共聚物的热敏性质的可生物降解的三嵌段共聚物微球用于药物递送。
6. Formation of Monodisperse Carbon Spheres with Tunable Size via Triblock Copolymer-Assisted Synthesis and Their Capacitor Properties [O] . Zhongguan Liang, Luomeng Zhang, Hao Liu, 2019

机译：三嵌段共聚物辅助合成可调节大小的单分散碳球的形成及其电容器性能
7. Engineering Plastics-Recent Developments in Synthesis and Applications. Changes in Morphology and Mechanical Properties with Composition for Microphase-Separated Polystyrene-block-Poly(ethylene-co-but-1-ene)-block-Polystyrene Triblock Copolymers. [O] . Hideo UMEDA, Shinichi SAKURAI, Yuichi KITAGAWA, 1997

机译：工程塑料 - 最近的合成和应用的发展。与微相分离聚苯乙烯 - 嵌段 - 聚（乙烯-Co-But-1-eNE） - Block-聚苯乙烯三嵌段共聚物的形态和力学性能变化。

New Comb-Shaped Triblock Copolymers Containing a Liquid-Crystalline Block and Polyvinylpyridine Amorphous Blocks: Synthesis and Properties

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