Lead Carbodiimides Related to the Mineral Bideauxite

Dolabdjian Konstantin; Meyer Hans‐Jürgen

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Lead Carbodiimides Related to the Mineral Bideauxite

机译：铅碳二酰亚胺与矿物竞技有关

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> Solid state metathesis reactions of PbCl ₂ with metal carbodiimides yielded multinary lead carbodiimide chlorides A Pb ₂ Cl ₃ (CN ₂ ) ( A = Li, Na, Ag). Their crystal structures strongly relate to the mineral Bideauxite [AgPb ₂ Cl ₃ (OH,F) ₂ ], all crystallizing in the space group Fd cssStyle="text-decoration:overline">3 m . The same crystal structure exists not only with chloride but also with bromide. Another compound obtained in this system is LiPbCl(CN ₂ ) with a crystal structure that can be considered as the result of an intercalation of LiCl into the layered structure of Pb(CN ₂ ).

机译： > Pbcl _{2 与金属碳二酰亚胺的固态复位反应产生了多元碳二亚胺氯化物 a Pb _{2 CL _{3 （cn _{2 ）（ a = li，na，Ag）。它们的晶体结构与矿物竞技态有敏感[AGPB _{2 CL _{3 （OH，f）_{2 ]，所有空间组中都结晶< i> fd cssstyle =“文本装饰：overline”> 3 m 。相同的晶体结构不仅存在氯化物，还存在溴化物。在该系统中获得的另一种化合物是Lipbcl（CN _{2 ），其晶体结构可以被认为是LICL进入PB的分层结构的结果（CN _{2 ）。}}}}}}}}}

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2017年第23期|共6页
作者
Dolabdjian Konstantin; Meyer Hans‐Jürgen;
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作者单位

Abteilung für Festk?rperchemie und Theoretische Anorganische ChemieUniversit?t TübingenAuf der Morgenstelle 18 72076 Tübingen Germany;

Abteilung für Festk?rperchemie und Theoretische Anorganische ChemieUniversit?t TübingenAuf der Morgenstelle 18 72076 Tübingen Germany;

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正文语种 eng
中图分类化学;
关键词
Bideauxite; Carbodiimide; Cyanamide; Lead; Solid state metathesis;

机译：竞斋零;碳二亚胺;氰酰胺;铅;固态复分解;

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7. Lead Carbodiimides Related to the Mineral Bideauxite [O] . Konstantin Dolabdjian, Hans-Jürgen Meyer 2017

机译：铅碳二酰亚胺与矿物竞技有关

Lead Carbodiimides Related to the Mineral Bideauxite

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