Synthesis, Characterization, and Fluorescence Chemosensor Properties of a cis-Dioxomolybdenum(VI) Complex Containing Multidentate Hydrazone Ligands

Kurbah Sunshine Dominic; Kumar Arvind; Shangpung Sankey; Syiemlieh Ibanphylla; Khongjoh Iohboklang; Lal Ram Ashray

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Synthesis, Characterization, and Fluorescence Chemosensor Properties of a cis-Dioxomolybdenum(VI) Complex Containing Multidentate Hydrazone Ligands

机译：CIS-DIOxomolomboldenum（VI）复合物的合成，表征和荧光化学传感器特性含有多型腙配体的络合物

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The homobimetallic molybdenum(VI) complex, [(MoO2)(2)(slsch)(DMF)(2)], derived from multidentate hydrazone ligand (H(4)slsch = disalicylaldehyde succinoyldihydrazone) was synthesized. The complex was obtained by reaction of the ligand with Mo-2(acac)(2) in 1: 2 molar ratio in methanol. It was characterized by using various spectroscopic techniques. The structure of the complex was established by single crystal X-ray diffraction. The complex shows fluorescence emission, responds toward Al-III ions, and hence it can be used as fluorescence chemosensor for sensing Al-III ions. The sensing properties show that the complex is more efficient and sensitive towards Al-III ions than the rest of the ions used in the presented study.

机译：合成衍生自多送腙配体（H（4）SLSCH =脱硅氧丙基琥珀酰甲酰霉酰肼）的均多金属钼（5）络合物，[（MOO2）（2）（2）（SLSCH）（2）（DMF）（2））。通过甲醇中的1：2摩尔比在1：2摩尔比中的MO-2（ACAC）（2）反应得到该复合物。它的特征在于使用各种光谱技术。通过单晶X射线衍射建立复合物的结构。该复合物显示荧光发射，响应Al-III离子，因此它可以用作感测Al-III离子的荧光化学传感器。传感特性表明，该复合物对Al-III离子更有效和敏感，而不是所提出的研究中使用的其他离子。

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2017年第13期|共8页
作者
Kurbah Sunshine Dominic; Kumar Arvind; Shangpung Sankey; Syiemlieh Ibanphylla; Khongjoh Iohboklang; Lal Ram Ashray;
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作者单位

North Eastern Hill Univ Dept Chem Ctr Adv Studies Shillong 793022 Meghalaya India;

Univ West Indies Fac Sci &

Technol Dept Chem St Augustine Trinid &

Tobago;

North Eastern Hill Univ Dept Chem Ctr Adv Studies Shillong 793022 Meghalaya India;

North Eastern Hill Univ Dept Chem Ctr Adv Studies Shillong 793022 Meghalaya India;

North Eastern Hill Univ Dept Chem Ctr Adv Studies Shillong 793022 Meghalaya India;

North Eastern Hill Univ Dept Chem Ctr Adv Studies Shillong 793022 Meghalaya India;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Bimetallic; Crystal structure; Fluorescence; H-1 NMR; Molybdenum;

机译：Bimetallic;晶体结构;荧光;H-1 NMR;钼;

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1. Synthesis, Characterization, and Fluorescence Chemosensor Properties of a cis-Dioxomolybdenum(VI) Complex Containing Multidentate Hydrazone Ligands [J] . Kurbah Sunshine Dominic, Kumar Arvind, Shangpung Sankey, Zeitschrift fur Anorganische und Allgemeine Chemie . 2017,第13期

机译：CIS-DIOxomolomboldenum（VI）复合物的合成，表征和荧光化学传感器特性含有多型腙配体的络合物
2. Synthesis and structural characterization of zinc(II) and cobalt(II) complexes based on multidentate hydrazone ligands [J] . Li Li, Zhang Yuan Zhuo, Liu E., Journal of Molecular Structure . 2016,第Null期

机译：基于多齿配体的锌（II）和钴（II）配合物的合成和结构表征
3. cis-Dioxomolybdenum(VI) complexes of a new ONN chelating thiosemicarbazidato ligand; Synthesis, characterization, crystal, molecular structures and antioxidant activities [J] . Ceylan Berat Ilhan, Deniz Nahide Gulsah, Kahraman Sibel, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2015,第Null期

机译：新的ONN螯合硫代氨基脲化合物的顺式-二氧钼（VI）配合物;合成，表征，晶体，分子结构和抗氧化活性
4. Synthesis, Characterization and Biological Activity Evaluation of Novel Pd(II) and Pt(II) Complexes with Heterocyclic Hydrazone Ligands [C] . N. R. Filipovic, T. R. Todorovic, D. M. Sladic, Yugoslav Materials Restarch Society Conference . 2007

机译：用杂环腙配体的新型Pd（II）和Pt（II）配合物的合成，表征和生物活性评价
5. The Gas Chromatographic Separation Properties of Azulene and the Synthesis and Characterization of Bulky Bis-pyrazolylpyridine Metal-Ligand Complexes [D] . Jackson, Matthew Todd. 2018

机译：腈的气相色谱分离特性及大体积双-吡唑基吡啶金属-配体的合成与表征
6. Synthesis Characterization and Biological Activities of Cu(II) Co(II) Mn(II) Fe(II) and UO2(VI) Complexes with a New Schiff Base Hydrazone: O-Hydroxyacetophenone-7-chloro-4-quinoline Hydrazone [O] . Nora H. Al-Shaalan 2011

机译：具有新型席夫碱Hy的Cu（II）Co（II）Mn（II）Fe（II）和UO2（VI）配合物的合成表征和生物活性：O-羟基乙酰苯酮-7-chloro-4-喹Hy Hy
7. >Synthesis, characterization and ion sensing properties of a new colorimetric chemosensor based on an hydrazone moiety [O] . M. Manuela Raposo, R. Cristina M. Ferreira, Susana P. Costa 2017

机译：<浓度>基于腙部分的新比色化学传感器的合成，表征和离子感测性能

Synthesis, Characterization, and Fluorescence Chemosensor Properties of a cis-Dioxomolybdenum(VI) Complex Containing Multidentate Hydrazone Ligands

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