Four novel N3O4 donor macrocycles and their lanthanide(III) complexes

Bertolo E.; de Blas A.; Fenton DE.; Macias A.; Rodriguez A. Rodriguez-Blas T.; Villar A.; Bastida R.

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Four novel N3O4 donor macrocycles and their lanthanide(III) complexes

机译：四个新的N3O4供体宏杂种及其镧系元素（III）配合物

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A new series of lanthanide(III) complexes with two novel Schiff-base macrocycles, L-1 and L-2, containing a N3O4 donor set have been prepared by cyclocondensation of 2,6-bis(2-formylphenoxymethyl)pyridine and 1,2-bis(2-aminophenoxy)ethane or 1,3-bis(2-aminophenoxy)propane, respectively, in the presence of the appropriate metal salt as a template agent. In the absence of the metal salt the macrocycles are not formed. The diamine macrocycles L-3 and L-4 are also formed by reaction of the corresponding diamine and dicarbonyl precursors followed by an in situ reduction with NaBH4. Their complexation potential towards Ln(III) ions were also investigated. [References: 40]

机译：通过2,6-双（2-甲酰甲甲基甲基）吡啶的环核化制备了具有两种新型席克基碱基宏杂种，L-1和L-2的新型镧系元素（III）络合物，其中包含N3O4供体组。在适当的金属盐存在作为模板剂的情况下，分别在适当的金属盐存在下分别为2-双（2-氨基氧基氧基）丙烷或1,3-双（2-氨基氧基）丙烷。在没有金属盐的情况下，未形成宏键。二胺宏茂的L-3和L-4也通过相应的二胺和二羰基前体的反应而形成，然后用NaBH 4反应。还研究了它们对LN（III）离子的络合潜力。 [参考：40]

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来源
《Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences》 |1998年第12期|共10页
作者
Bertolo E.; de Blas A.; Fenton DE.; Macias A.; Rodriguez A. Rodriguez-Blas T.; Villar A.; Bastida R.;
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作者单位

Univ Santiago Dept Quim Inorgan Avda Ciencias S-N Santiago De Compostela 15706 Spain.;

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正文语种 eng
中图分类化学;
关键词
Template synthesis; Lanthanide(iii) complexes; Oxaazamacrocycle; Schiff-base; Ion selectivity; Schiff-base complexes; Crystal-structure; Nickel(ii) complex; Ligands; Actinides; Oxygen; Units; Ions;

机译：模板合成;镧系元素（III）络合物;氧化血管植被;席克属碱;离子选择性;Schiff-Base络合物;晶体结构;镍（II）复合物;配体;辐射素;氧气;单位;单位;离子;

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1. Four novel N3O4 donor macrocycles and their lanthanide(III) complexes [J] . Bertolo E., de Blas A., Fenton DE., Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 1998,第12期

机译：四个新的N3O4供体宏杂种及其镧系元素（III）配合物
2. Lanthanide(III) Complexes of Two Novel N_3O_4-donor Macrocycles Derived from 3,6-Dioxa-l,8-Octanediamine [J] . Emilia Bertolo, Rufina Bastida, Carlos Lodeiro, Journal of Inclusion Phenomena and Macrocyclic Chemistry . 2004,第3a4期

机译：3,6-二氧杂-1,8-辛二胺衍生的两个新型N_3O_4-供体大环的镧系元素（III）配合物
3. Lanthanide (III) perchlorate complexes of two 24 membered N_3O_4-donor macrocycles [J] . Emilia Bertolo, Rufina Bastida, David E. Fenton Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2001,第0期

机译：两个24元N_3O_4-供体大环化合物的镧系元素（III）高氯酸盐络合物
4. Lanthanide Enhanced Luminescence (LEL) with one and two photon excitation of Quantum Dyes~R Lanthanide(III)-Macrocycles [C] . Robert C. Leif, Margie C. Becker, Al Bromm Jr., Conference on Imaging, Manipulation, and Analysis of Biomolecules, Cells, and Tissues II; 20040127-20040128; San Jose,CA; US . 2004

机译：量子染料〜R镧系元素（III）-大环的一和两个光子激发的镧系元素增强发光（LEL）
5. Part I. Syntheses and characterization of hydrogen-bridged lanthanide(II)-boron complexes. Part II. Syntheses and characterization of cyanide-bridged lanthanide(III)-palladium complexes. [D] . Lim, Soyoung. 2001

机译：第一部分：氢桥联镧系元素（II）-硼配合物的合成与表征。第二部分氰化物桥联的镧系元素（III）-钯配合物的合成与表征。
6. Helical Lanthanide(III) Complexes with Chiral Nonaaza Macrocycle [O] . Janusz Gregoliński, Przemysław Starynowicz, KimNgan T. Hua, -1

机译：具有手性Nonaaza大环的螺旋镧系元素（III）配合物
7. Trinuclear and Hexanuclear Lanthanide(III) Complexes of the Chiral 3+3 Macrocycle: Xray Crystal Structures and Magnetic Properties [O] . -1

机译：手性3 + 3宏ycle的三核和六核镧系元素（III）复合物：X射线晶体结构和磁性

Four novel N3O4 donor macrocycles and their lanthanide(III) complexes

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