...
首页> 外文期刊>AIChE Journal >NMR Imaging of Low Pressure, Gas-Phase Transport in Packed Beds Using Hyperpolarized Xenon-129
【24h】

NMR Imaging of Low Pressure, Gas-Phase Transport in Packed Beds Using Hyperpolarized Xenon-129

机译:使用超极化Xenon-129在填充床中进行低压气相传输的NMR成像

获取原文
获取原文并翻译 | 示例
           

摘要

Gas-phase magnetic resonance imaging (MRI) has been used to investigate heterogeneity in mass transport in a packed bed of commercial, alumina, catalyst supports. Hyperpolarized Xe-129 MRI enables study of transient diffusion for microscopic porous systems using xenon chemical shift to selectively image gas within the pores, and, thence, permits study of low-density, gas-phase mass-transport, such that diffusion can be studied in the Knudsen regime, and not just the molecular regime, which is the limitation with other current techniques. Knudsen-regime diffusion is common in many industrial, catalytic processes. Significantly, larger spatial variability in mass transport rates across the packed bed was found compared to techniques using only molecular diffusion. It has thus been found that that these heterogeneities arise over length-scales much larger than similar to 100 mu m. (c) 2015 American Institute of Chemical Engineers.
机译:气相磁共振成像(MRI)已用于研究在商用氧化铝催化剂载体填充床中传质中的异质性。超极化Xe-129 MRI能够研究使用氙化学位移对孔中的气体进行选择性成像的微观多孔系统的瞬态扩散,因此可以研究低密度的气相传质,从而可以研究扩散在克努森(Knudsen)体制中,不仅限于分子体制,这是当前其他技术的局限性。努森制度的扩散在许多工业催化过程中很常见。值得注意的是,与仅使用分子扩散的技术相比,发现在整个填充床中的传质速率具有较大的空间变异性。因此发现,这些异质性在远大于100μm的长度尺度上出现。 (c)2015美国化学工程师学会。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号