Syntheses, Crystal Structures, and Fluorescent Properties of Two Mixed-Ligand Cadmium Coordination Polymers Based on Dicarboxylate and Bis-benzimidazole Ligands

Wen Yong-Hong; Chen Chang-Geng; Wen Hui-Ling; Mu Xiao-Wei; Yao Kuo

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Syntheses, Crystal Structures, and Fluorescent Properties of Two Mixed-Ligand Cadmium Coordination Polymers Based on Dicarboxylate and Bis-benzimidazole Ligands

机译：基于二羧酸二羧酸酯和双苯并咪唑配体的两个混合配体镉配位聚合物的合成，晶体结构和荧光性能

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Two cadmium(II) coordination polymers, {[Cd-2(HO-bdc)(Hbbop)(2)]}(n) (1), and {[Cd-2(H2N-bdc)(Hbbop)(2)]center dot 2(H2O)}(n) (2), (HO-H(2)bdc = 5-hydroxyisophthalic acid, H2N-H(2)bdc = 5-aminoisophthalic acid, and H(2)bbop = 1,3-bis(benzimidazol-2-yl)-2-oxapropane) have been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectra, single crystal X-ray diffraction, and thermogravimetric analyses. Their structures are 2D networks with (6(3)) topology, which are further connected by hydrogen bonds to form 3D supramolecular architectures. Additionally, fluorescent properties of the two complexes are reported.

机译：两个镉（II）配位聚合物，{[CD-2（HO-BDC）（HBBOP）（2）]}（N）（1），和{[CD-2（H2N-BDC）（HBBOP）（2） ]中心点2（H2O）}}（N）（2），（HO-H（2）BDC = 5-羟基邻苯二甲酸，H2N-H（2）BDC = 5-氨基间苯二甲酸，H（2）BBOP = 1 ，在水热条件下合成了3-双（Benzimidazol-2-Y1）-2-氧丙烷，其特征在于元素分析，IR光谱，单晶X射线衍射和热重分析。它们的结构是具有（6（3））拓扑的2D网络，其通过氢键进一步连接以形成3D超分子架构。另外，报道了两种配合物的荧光特性。

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来源
《Journal of chemical crystallography》 |2018年第2期|共7页
作者
Wen Yong-Hong; Chen Chang-Geng; Wen Hui-Ling; Mu Xiao-Wei; Yao Kuo;
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作者单位

Qingdao Univ Sci &

Technol State Key Lab Base Ecochem Engn Coll Chem &

Mol Engn Qingdao 266042 Peoples R China;

Qingdao Univ Sci &

Technol State Key Lab Base Ecochem Engn Coll Chem &

Mol Engn Qingdao 266042 Peoples R China;

Qingdao Univ Sci &

Technol State Key Lab Base Ecochem Engn Coll Chem &

Mol Engn Qingdao 266042 Peoples R China;

Qingdao Univ Sci &

Technol State Key Lab Base Ecochem Engn Coll Chem &

Mol Engn Qingdao 266042 Peoples R China;

Qingdao Univ Sci &

Technol State Key Lab Base Ecochem Engn Coll Chem &

Mol Engn Qingdao 266042 Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
Cadmium; Coordination polymer; Crystal structure; Luminescence;

机译：镉;配位聚合物;晶体结构;发光;

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1. Syntheses, Crystal Structures, and Fluorescent Properties of Two Mixed-Ligand Cadmium Coordination Polymers Based on Dicarboxylate and Bis-benzimidazole Ligands [J] . Wen Yong-Hong, Chen Chang-Geng, Wen Hui-Ling, Journal of chemical crystallography . 2018,第1a2期

机译：基于二羧酸二羧酸酯和双苯并咪唑配体的两个混合配体镉配位聚合物的合成，晶体结构和荧光性能
2. Hydrothermal Syntheses, Crystal Structures, and Photoluminescent Properties of Two New Cadmium(II) Coordination Polymers Based on Asymmetric Dicarboxylate and N-donor Ligands [J] . Hui Miao, Ying Wang, Yu-Min Cui, Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第7期

机译：基于不对称二羧酸盐和N供体配体的两种新型镉（II）配位聚合物的水热合成，晶体结构和光致发光性能
3. Two cadmium(II) coordination polymers constructed from dicarboxylate and bis(imidazole) ligands: Syntheses, crystal structures, luminescence and photocatalytic properties [J] . Zhou Hong, Yu Min, Liu Guang-Xiang Inorganica Chimica Acta . 2016,第Null期

机译：由二羧酸盐和双（咪唑）配体构成的两种镉（II）配位聚合物：合成，晶体结构，发光和光催化性能
4. Syntheses, Crystal Structures and Luminescence of Two Coordination Polymers Based on Isophthalic Acid and 2-(3-Pyridyl)benzimidazole Ligands [C] . Kefen Yue, Shuang Zhao, Ruili Zhao International Conference on Chemical, Material and Metallurgical Engineering . 2012

机译：基于间苯二甲酸和2-（3-吡啶基）苯并咪唑配体的两种配位聚合物的合成，晶体结构和发光
5. I. The synthesis and coordination chemistry of novel 1,1,1-tris(aminomethyl)ethane (TAME) derived ligands and their use as size selective fluorescent zinc(II) sensors. II. The synthesis of strongly and weakly binding ligands with nitrogen, oxygen, and sulfur-donor groups to be used as receptors in fluorescent ratiometric indicators for transition metal ions. [D] . Kennedy, Daniel Patrick. 2007

机译：I.新型1,1,1-三（氨基甲基）乙烷（TAME）衍生的配体的合成和配位化学及其作为尺寸选择荧光锌（II）传感器的用途。二。具有氮，氧和硫供体基团的强结合和弱结合配体的合成，将用作过渡金属离子的荧光比率指示剂中的受体。
6. Novel Energetic Coordination Polymers Based on 15-Di(nitramino)tetrazole With High Oxygen Content and Outstanding Properties: Syntheses Crystal Structures and Detonation Properties [O] . Yanan Li, Tao Yu, Yiying Zhang, -1

机译：基于15-二（硝胺基）四唑的新型高能配位聚合物具有较高的氧含量和优异的性能：合成晶体结构和爆轰性能
7. Correction: Syntheses, X-ray structures, gas adsorption and luminescent properties of three coordination polymers of Zn(ii) dicarboxylates mixed with a linear, neutral, and rigid N,N′-donor ligand [O] . Biswajit Bhattacharya, Dilip Kumar Maity, Rajdip Dey, 2015

机译：校正：Zn（II）二羧酸酯的三种配位聚合物的合成，X射线结构，气体吸附和发光性能与线性，中性和刚性N，N'-供体配体混合

Syntheses, Crystal Structures, and Fluorescent Properties of Two Mixed-Ligand Cadmium Coordination Polymers Based on Dicarboxylate and Bis-benzimidazole Ligands

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