Preparation and characterization of single crystals of tetrakis(4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyl)germane

Lee Tae Won; Lee Dong Woo; Choi Yeonjeong; Ok Kang Min; Park Kwangyong

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Preparation and characterization of single crystals of tetrakis(4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyl)germane

机译：单晶体（4-（5,5-二甲基-2-苯基-1,3-二氧-2-基）苯基）衍生物的单晶的制备及表征

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摘要

A novel tetrakis(4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyl)germane (2) was synthesized by the reaction of germanium(IV) tetrachloride with 4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyllithium. Colorless plate-shaped single crystals obtained from recrystallization in ether were characterized by the single-crystal X-ray diffraction. The organogermanium compound was crystallized in a noncentrosymmetric nonpolar tetragonal space group, 1-4, and classified as a porous molecular material owing to the presence of two types of distinct channels as a result of intermolecular hydrogen bonding. Compound 2 exhibits a differential gas adsorption property. The powder second-harmonic generating (SHG) measurements indicate that compound 2 shows a SHG efficiency 10 times greater than those of alpha-SiO2 and type-1 nonphase-matchable. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

机译：通过锗（IV）四氯化物的反应合成新的四溴铵（4-（5,5-二甲基-2-苯基-1,3-二氧化硅-2-基）苯基）锗（2），其中四氯化物与4-（5， 5-二甲基-2-苯基-1,3-二氧烷-2-基）苯基锂。通过单晶X射线衍射在乙醚中重结晶获得的无色板状单晶。由于由于分子间氢粘合而存在两种不同通道的存在，有机合金化合物在非致重非极性四方空间组，1-4中被分类为多孔分子材料。化合物2表现出差动气体吸附性。粉末二次谐波产生（SHG）测量表明化合物2显示了比α-SiO2的10倍和1型非相匹配的SHG效率。（c）2018年韩国工程和工程化学学会。 elsevier b.v出版。保留所有权利。

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《Journal of industrial and engineering chemistry》 |2019年第2019期|共5页
作者
Lee Tae Won; Lee Dong Woo; Choi Yeonjeong; Ok Kang Min; Park Kwangyong;
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作者单位

Chung Ang Univ Sch Chem Engn &

Mat Sci Seoul 06974 South Korea;

Chung Ang Univ Dept Chem Seoul 06974 South Korea;

Chung Ang Univ Sch Chem Engn &

Mat Sci Seoul 06974 South Korea;

Chung Ang Univ Dept Chem Seoul 06974 South Korea;

Chung Ang Univ Sch Chem Engn &

Mat Sci Seoul 06974 South Korea;

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正文语种 eng
中图分类化学工业;
关键词
Organogermanium compound; Single crystal; Tetrahedral; Gas adsorption; Second-harmonic generating efficiency;

机译：有机吡喃化合物;单晶;四面体;气体吸附;二次谐波产生效率;

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Preparation and characterization of single crystals of tetrakis(4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyl)germane

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